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Elevated-Temperature Space Charge Characteristics and Trapping Mechanism of Cross-Linked Polyethylene Modified by UV-Initiated Grafting MAH
Space charge characteristics of cross-linked polyethylene (XLPE) at elevated temperatures have been evidently improved by the graft modifications with ultraviolet (UV) initiation technique, which can be efficiently utilized in industrial cable manufactures. Maleic anhydride (MAH) of representative c...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7504756/ https://www.ncbi.nlm.nih.gov/pubmed/32878192 http://dx.doi.org/10.3390/molecules25173973 |
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author | Zhao, Hong Xi, Chen Zhao, Xin-Dong Sun, Wei-Feng |
author_facet | Zhao, Hong Xi, Chen Zhao, Xin-Dong Sun, Wei-Feng |
author_sort | Zhao, Hong |
collection | PubMed |
description | Space charge characteristics of cross-linked polyethylene (XLPE) at elevated temperatures have been evidently improved by the graft modifications with ultraviolet (UV) initiation technique, which can be efficiently utilized in industrial cable manufactures. Maleic anhydride (MAH) of representative cyclic anhydride has been successfully grafted onto polyethylene molecules through UV irradiation process. Thermal stimulation currents and space charge characteristics at the elevated temperatures are coordinately analyzed to elucidate the trapping behavior of blocking charge injection and impeding carrier transport which is caused by grafting MAH. It is also verified from the first-principles calculations that the bound states as charge carrier traps can be introduced by grafting MAH onto polyethylene molecules. Compared with pure XLPE, the remarkably suppressed space charge accumulations at high temperatures have been achieved in XLPE-g-MAH. The polar groups on the grafted MAH can provide deep traps in XLPE-g-MAH, which will increase charge injection barrier by forming a charged layer of Coulomb-potential screening near electrodes and simultaneously reduce the electrical mobility of charge carriers by trap-carrier scattering, resulting in an appreciable suppression of space charge accumulations inside material. The exact consistence of experimental results with the quantum mechanics calculations demonstrates a promising routine for the modification strategy of grafting polar molecules with UV initiation technique in the development of high-voltage DC cable materials. |
format | Online Article Text |
id | pubmed-7504756 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-75047562020-09-26 Elevated-Temperature Space Charge Characteristics and Trapping Mechanism of Cross-Linked Polyethylene Modified by UV-Initiated Grafting MAH Zhao, Hong Xi, Chen Zhao, Xin-Dong Sun, Wei-Feng Molecules Article Space charge characteristics of cross-linked polyethylene (XLPE) at elevated temperatures have been evidently improved by the graft modifications with ultraviolet (UV) initiation technique, which can be efficiently utilized in industrial cable manufactures. Maleic anhydride (MAH) of representative cyclic anhydride has been successfully grafted onto polyethylene molecules through UV irradiation process. Thermal stimulation currents and space charge characteristics at the elevated temperatures are coordinately analyzed to elucidate the trapping behavior of blocking charge injection and impeding carrier transport which is caused by grafting MAH. It is also verified from the first-principles calculations that the bound states as charge carrier traps can be introduced by grafting MAH onto polyethylene molecules. Compared with pure XLPE, the remarkably suppressed space charge accumulations at high temperatures have been achieved in XLPE-g-MAH. The polar groups on the grafted MAH can provide deep traps in XLPE-g-MAH, which will increase charge injection barrier by forming a charged layer of Coulomb-potential screening near electrodes and simultaneously reduce the electrical mobility of charge carriers by trap-carrier scattering, resulting in an appreciable suppression of space charge accumulations inside material. The exact consistence of experimental results with the quantum mechanics calculations demonstrates a promising routine for the modification strategy of grafting polar molecules with UV initiation technique in the development of high-voltage DC cable materials. MDPI 2020-08-31 /pmc/articles/PMC7504756/ /pubmed/32878192 http://dx.doi.org/10.3390/molecules25173973 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Zhao, Hong Xi, Chen Zhao, Xin-Dong Sun, Wei-Feng Elevated-Temperature Space Charge Characteristics and Trapping Mechanism of Cross-Linked Polyethylene Modified by UV-Initiated Grafting MAH |
title | Elevated-Temperature Space Charge Characteristics and Trapping Mechanism of Cross-Linked Polyethylene Modified by UV-Initiated Grafting MAH |
title_full | Elevated-Temperature Space Charge Characteristics and Trapping Mechanism of Cross-Linked Polyethylene Modified by UV-Initiated Grafting MAH |
title_fullStr | Elevated-Temperature Space Charge Characteristics and Trapping Mechanism of Cross-Linked Polyethylene Modified by UV-Initiated Grafting MAH |
title_full_unstemmed | Elevated-Temperature Space Charge Characteristics and Trapping Mechanism of Cross-Linked Polyethylene Modified by UV-Initiated Grafting MAH |
title_short | Elevated-Temperature Space Charge Characteristics and Trapping Mechanism of Cross-Linked Polyethylene Modified by UV-Initiated Grafting MAH |
title_sort | elevated-temperature space charge characteristics and trapping mechanism of cross-linked polyethylene modified by uv-initiated grafting mah |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7504756/ https://www.ncbi.nlm.nih.gov/pubmed/32878192 http://dx.doi.org/10.3390/molecules25173973 |
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