Cargando…

Highly UV Resistant Inch‐Scale Hybrid Perovskite Quantum Dot Papers

Halide perovskite quantum dots (PQDs) are promising materials for diverse applications including displays, light‐emitting diodes, and solar cells due to their intriguing properties such as tunable bandgap, high photoluminescence quantum yield, high absorbance, and narrow emission peaks. Despite the...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Ting‐You, Xu, Xuezhu, Lin, Chun‐Ho, Guan, Xinwei, Hsu, Wei‐Hao, Tsai, Meng‐Lin, Fang, Xiaosheng, Wu, Tom, He, Jr‐Hau
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7507066/
https://www.ncbi.nlm.nih.gov/pubmed/32995112
http://dx.doi.org/10.1002/advs.201902439
_version_ 1783585155135307776
author Li, Ting‐You
Xu, Xuezhu
Lin, Chun‐Ho
Guan, Xinwei
Hsu, Wei‐Hao
Tsai, Meng‐Lin
Fang, Xiaosheng
Wu, Tom
He, Jr‐Hau
author_facet Li, Ting‐You
Xu, Xuezhu
Lin, Chun‐Ho
Guan, Xinwei
Hsu, Wei‐Hao
Tsai, Meng‐Lin
Fang, Xiaosheng
Wu, Tom
He, Jr‐Hau
author_sort Li, Ting‐You
collection PubMed
description Halide perovskite quantum dots (PQDs) are promising materials for diverse applications including displays, light‐emitting diodes, and solar cells due to their intriguing properties such as tunable bandgap, high photoluminescence quantum yield, high absorbance, and narrow emission peaks. Despite the prosperous achievements over the past several years, PQDs face severe challenges in terms of stability under different circumstances. Currently, researchers have overcome part of the stability problem, making PQDs sustainable in water, oxygen, and polar solvents for long‐term use. However, halide PQDs are easily degraded under continuous irradiation, which significantly limits their potential for conventional applications. In this study, an oleic acid/oleylamine (traditional surface ligands)‐free method to fabricate perovskite quantum dot papers (PQDP) is developed by adding cellulose nanocrystals as long‐chain binding ligands that stabilize the PQD structure. As a result, the relative photoluminescence intensity of PQDP remains over ≈90% under continuous ultraviolet (UV, 16 W) irradiation for 2 months, showing negligible photodegradation. This proposed method paves the way for the fabrication of ultrastable PQDs and the future development of related applications.
format Online
Article
Text
id pubmed-7507066
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-75070662020-09-28 Highly UV Resistant Inch‐Scale Hybrid Perovskite Quantum Dot Papers Li, Ting‐You Xu, Xuezhu Lin, Chun‐Ho Guan, Xinwei Hsu, Wei‐Hao Tsai, Meng‐Lin Fang, Xiaosheng Wu, Tom He, Jr‐Hau Adv Sci (Weinh) Communications Halide perovskite quantum dots (PQDs) are promising materials for diverse applications including displays, light‐emitting diodes, and solar cells due to their intriguing properties such as tunable bandgap, high photoluminescence quantum yield, high absorbance, and narrow emission peaks. Despite the prosperous achievements over the past several years, PQDs face severe challenges in terms of stability under different circumstances. Currently, researchers have overcome part of the stability problem, making PQDs sustainable in water, oxygen, and polar solvents for long‐term use. However, halide PQDs are easily degraded under continuous irradiation, which significantly limits their potential for conventional applications. In this study, an oleic acid/oleylamine (traditional surface ligands)‐free method to fabricate perovskite quantum dot papers (PQDP) is developed by adding cellulose nanocrystals as long‐chain binding ligands that stabilize the PQD structure. As a result, the relative photoluminescence intensity of PQDP remains over ≈90% under continuous ultraviolet (UV, 16 W) irradiation for 2 months, showing negligible photodegradation. This proposed method paves the way for the fabrication of ultrastable PQDs and the future development of related applications. John Wiley and Sons Inc. 2020-07-24 /pmc/articles/PMC7507066/ /pubmed/32995112 http://dx.doi.org/10.1002/advs.201902439 Text en © 2020 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Li, Ting‐You
Xu, Xuezhu
Lin, Chun‐Ho
Guan, Xinwei
Hsu, Wei‐Hao
Tsai, Meng‐Lin
Fang, Xiaosheng
Wu, Tom
He, Jr‐Hau
Highly UV Resistant Inch‐Scale Hybrid Perovskite Quantum Dot Papers
title Highly UV Resistant Inch‐Scale Hybrid Perovskite Quantum Dot Papers
title_full Highly UV Resistant Inch‐Scale Hybrid Perovskite Quantum Dot Papers
title_fullStr Highly UV Resistant Inch‐Scale Hybrid Perovskite Quantum Dot Papers
title_full_unstemmed Highly UV Resistant Inch‐Scale Hybrid Perovskite Quantum Dot Papers
title_short Highly UV Resistant Inch‐Scale Hybrid Perovskite Quantum Dot Papers
title_sort highly uv resistant inch‐scale hybrid perovskite quantum dot papers
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7507066/
https://www.ncbi.nlm.nih.gov/pubmed/32995112
http://dx.doi.org/10.1002/advs.201902439
work_keys_str_mv AT litingyou highlyuvresistantinchscalehybridperovskitequantumdotpapers
AT xuxuezhu highlyuvresistantinchscalehybridperovskitequantumdotpapers
AT linchunho highlyuvresistantinchscalehybridperovskitequantumdotpapers
AT guanxinwei highlyuvresistantinchscalehybridperovskitequantumdotpapers
AT hsuweihao highlyuvresistantinchscalehybridperovskitequantumdotpapers
AT tsaimenglin highlyuvresistantinchscalehybridperovskitequantumdotpapers
AT fangxiaosheng highlyuvresistantinchscalehybridperovskitequantumdotpapers
AT wutom highlyuvresistantinchscalehybridperovskitequantumdotpapers
AT hejrhau highlyuvresistantinchscalehybridperovskitequantumdotpapers