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Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with dppf-Nickel(0)
[Image: see text] The mechanism of the reactions between dppf-Ni(0) complexes and alkyl halides has been investigated using kinetic and mechanistic experiments and DFT calculations. The active species is [Ni(κ(2)-dppf)(κ(1)-dppf)], which undergoes a halide abstraction reaction with alkyl halides and...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7507766/ https://www.ncbi.nlm.nih.gov/pubmed/32983589 http://dx.doi.org/10.1021/acscatal.0c02514 |