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Does the crystal structure of vanadium nitrogenase contain a reaction intermediate? Evidence from quantum refinement
ABSTRACT: Recently, a crystal structure of V-nitrogenase was presented, showing that one of the µ(2) sulphide ions in the active site (S2B) is replaced by a lighter atom, suggested to be NH or NH(2), i.e. representing a reaction intermediate. Moreover, a sulphur atom is found 7 Å from the S2B site,...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Berlin Heidelberg
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7511287/ https://www.ncbi.nlm.nih.gov/pubmed/32856107 http://dx.doi.org/10.1007/s00775-020-01813-z |