Cargando…
Coarse Graining, Nonmaximal Entropy, and Power Laws
We show that coarse graining produces significant and predictable effects on the entropy of states of equilibrium when the scale of coarse graining becomes comparable to that of density fluctuations. We demonstrate that a coarse-grained entropy typically evolves toward a state of effective equilibri...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7512300/ https://www.ncbi.nlm.nih.gov/pubmed/33265826 http://dx.doi.org/10.3390/e20100737 |
_version_ | 1783586126223638528 |
---|---|
author | Pérez-Cárdenas, Fernando C. Resca, Lorenzo Pegg, Ian L. |
author_facet | Pérez-Cárdenas, Fernando C. Resca, Lorenzo Pegg, Ian L. |
author_sort | Pérez-Cárdenas, Fernando C. |
collection | PubMed |
description | We show that coarse graining produces significant and predictable effects on the entropy of states of equilibrium when the scale of coarse graining becomes comparable to that of density fluctuations. We demonstrate that a coarse-grained entropy typically evolves toward a state of effective equilibrium with a lower value than that of the state of maximum entropy theoretically possible. The finer the coarse graining, the greater the drop in effective entropy, and the more relevant the fluctuations around that. Fundamental considerations allow us to derive a remarkable power law that relates coarse graining to the effective entropy gap. Another power law is found that precisely relates the noise range of effective entropy fluctuations to coarse graining. We test both power laws with numerical simulations based on a well-studied two-dimensional lattice gas model. As expected, the effects of these power laws diminish as our description approaches a macroscopic level, eventually disappearing in the thermodynamic limit, where the maximum entropy principle is reasserted. |
format | Online Article Text |
id | pubmed-7512300 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-75123002020-11-09 Coarse Graining, Nonmaximal Entropy, and Power Laws Pérez-Cárdenas, Fernando C. Resca, Lorenzo Pegg, Ian L. Entropy (Basel) Article We show that coarse graining produces significant and predictable effects on the entropy of states of equilibrium when the scale of coarse graining becomes comparable to that of density fluctuations. We demonstrate that a coarse-grained entropy typically evolves toward a state of effective equilibrium with a lower value than that of the state of maximum entropy theoretically possible. The finer the coarse graining, the greater the drop in effective entropy, and the more relevant the fluctuations around that. Fundamental considerations allow us to derive a remarkable power law that relates coarse graining to the effective entropy gap. Another power law is found that precisely relates the noise range of effective entropy fluctuations to coarse graining. We test both power laws with numerical simulations based on a well-studied two-dimensional lattice gas model. As expected, the effects of these power laws diminish as our description approaches a macroscopic level, eventually disappearing in the thermodynamic limit, where the maximum entropy principle is reasserted. MDPI 2018-09-26 /pmc/articles/PMC7512300/ /pubmed/33265826 http://dx.doi.org/10.3390/e20100737 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Pérez-Cárdenas, Fernando C. Resca, Lorenzo Pegg, Ian L. Coarse Graining, Nonmaximal Entropy, and Power Laws |
title | Coarse Graining, Nonmaximal Entropy, and Power Laws |
title_full | Coarse Graining, Nonmaximal Entropy, and Power Laws |
title_fullStr | Coarse Graining, Nonmaximal Entropy, and Power Laws |
title_full_unstemmed | Coarse Graining, Nonmaximal Entropy, and Power Laws |
title_short | Coarse Graining, Nonmaximal Entropy, and Power Laws |
title_sort | coarse graining, nonmaximal entropy, and power laws |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7512300/ https://www.ncbi.nlm.nih.gov/pubmed/33265826 http://dx.doi.org/10.3390/e20100737 |
work_keys_str_mv | AT perezcardenasfernandoc coarsegrainingnonmaximalentropyandpowerlaws AT rescalorenzo coarsegrainingnonmaximalentropyandpowerlaws AT peggianl coarsegrainingnonmaximalentropyandpowerlaws |