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Highly Active Wood-Derived Nitrogen-Doped Carbon Catalyst for the Oxygen Reduction Reaction

[Image: see text] In this recent decade, great interest has risen to develop metal-free and cheap, biomass-derived electrocatalysts for oxygen reduction reaction (ORR). Herein, we report a facile strategy to synthesize an electrochemically active nanocarbon material from the renewable and biological...

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Autores principales: Kaare, Kätlin, Yu, Eric, Volperts, Aleksandrs, Dobele, Galina, Zhurinsh, Aivars, Dyck, Alexander, Niaura, Gediminas, Tamasauskaite-Tamasiunaite, Loreta, Norkus, Eugenijus, Andrulevičius, Mindaugas, Danilson, Mati, Kruusenberg, Ivar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7512441/
https://www.ncbi.nlm.nih.gov/pubmed/32984677
http://dx.doi.org/10.1021/acsomega.0c01974
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author Kaare, Kätlin
Yu, Eric
Volperts, Aleksandrs
Dobele, Galina
Zhurinsh, Aivars
Dyck, Alexander
Niaura, Gediminas
Tamasauskaite-Tamasiunaite, Loreta
Norkus, Eugenijus
Andrulevičius, Mindaugas
Danilson, Mati
Kruusenberg, Ivar
author_facet Kaare, Kätlin
Yu, Eric
Volperts, Aleksandrs
Dobele, Galina
Zhurinsh, Aivars
Dyck, Alexander
Niaura, Gediminas
Tamasauskaite-Tamasiunaite, Loreta
Norkus, Eugenijus
Andrulevičius, Mindaugas
Danilson, Mati
Kruusenberg, Ivar
author_sort Kaare, Kätlin
collection PubMed
description [Image: see text] In this recent decade, great interest has risen to develop metal-free and cheap, biomass-derived electrocatalysts for oxygen reduction reaction (ORR). Herein, we report a facile strategy to synthesize an electrochemically active nanocarbon material from the renewable and biological resource, wood biomass. The ORR activity of the catalyst material was investigated in 0.1 M KOH solution by employing the rotating disc electrode method. Scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy were employed to obtain more information about the catalyst material’s morphology and composition. The material exhibits outstanding electrocatalytic activity with low onset potential and high current density, similar to that of a commercial Pt/C catalyst in an alkaline medium. The results clearly ascertain that wooden biomass can be easily transformed into novel carbon nanostructures with superior ORR activity and possibility to be used in fuel cells and metal–air batteries.
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spelling pubmed-75124412020-09-25 Highly Active Wood-Derived Nitrogen-Doped Carbon Catalyst for the Oxygen Reduction Reaction Kaare, Kätlin Yu, Eric Volperts, Aleksandrs Dobele, Galina Zhurinsh, Aivars Dyck, Alexander Niaura, Gediminas Tamasauskaite-Tamasiunaite, Loreta Norkus, Eugenijus Andrulevičius, Mindaugas Danilson, Mati Kruusenberg, Ivar ACS Omega [Image: see text] In this recent decade, great interest has risen to develop metal-free and cheap, biomass-derived electrocatalysts for oxygen reduction reaction (ORR). Herein, we report a facile strategy to synthesize an electrochemically active nanocarbon material from the renewable and biological resource, wood biomass. The ORR activity of the catalyst material was investigated in 0.1 M KOH solution by employing the rotating disc electrode method. Scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy were employed to obtain more information about the catalyst material’s morphology and composition. The material exhibits outstanding electrocatalytic activity with low onset potential and high current density, similar to that of a commercial Pt/C catalyst in an alkaline medium. The results clearly ascertain that wooden biomass can be easily transformed into novel carbon nanostructures with superior ORR activity and possibility to be used in fuel cells and metal–air batteries. American Chemical Society 2020-09-11 /pmc/articles/PMC7512441/ /pubmed/32984677 http://dx.doi.org/10.1021/acsomega.0c01974 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Kaare, Kätlin
Yu, Eric
Volperts, Aleksandrs
Dobele, Galina
Zhurinsh, Aivars
Dyck, Alexander
Niaura, Gediminas
Tamasauskaite-Tamasiunaite, Loreta
Norkus, Eugenijus
Andrulevičius, Mindaugas
Danilson, Mati
Kruusenberg, Ivar
Highly Active Wood-Derived Nitrogen-Doped Carbon Catalyst for the Oxygen Reduction Reaction
title Highly Active Wood-Derived Nitrogen-Doped Carbon Catalyst for the Oxygen Reduction Reaction
title_full Highly Active Wood-Derived Nitrogen-Doped Carbon Catalyst for the Oxygen Reduction Reaction
title_fullStr Highly Active Wood-Derived Nitrogen-Doped Carbon Catalyst for the Oxygen Reduction Reaction
title_full_unstemmed Highly Active Wood-Derived Nitrogen-Doped Carbon Catalyst for the Oxygen Reduction Reaction
title_short Highly Active Wood-Derived Nitrogen-Doped Carbon Catalyst for the Oxygen Reduction Reaction
title_sort highly active wood-derived nitrogen-doped carbon catalyst for the oxygen reduction reaction
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7512441/
https://www.ncbi.nlm.nih.gov/pubmed/32984677
http://dx.doi.org/10.1021/acsomega.0c01974
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