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Regio- and Stereoselective Synthesis of the Core Structure of Hexahydrobenzo[c]phenanthridine Alkaloids via Redox-Neutral Cp*Rh(III)-Catalyzed C–H/N–H Annulation of Cyclic Alkenes with Benzamides
[Image: see text] A highly stereo- and regioselective synthesis of the core skeleton of hexahydrobenzo[c]phenanthridine-type alkaloids is reported herein for the first time. A wide range of substrate scope, excellent functional group tolerance, and good to excellent yields were observed. This protoc...
Autores principales: | Das Adhikari, Gopal Krushna, Chebolu, Rajesh, Ravikumar, Ponneri Chandrababu |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7513371/ https://www.ncbi.nlm.nih.gov/pubmed/32984725 http://dx.doi.org/10.1021/acsomega.0c03434 |
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Correction
to “Rh(III)-Catalyzed Cyclopropanation
Initiated by C–H Activation: Ligand Development Enables a Diastereoselective
[2 + 1] Annulation of N-Enoxyphthalimides and Alkenes”
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