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Soft Heteroleptic N-Heterocyclic Carbene Palladium(II) Species for Efficient Catalytic Routes to Alkynones via Carbonylative Sonogashira Coupling

[Image: see text] N,N′-Substituted di-isopropyl (NHC-1), benzyl-isopropyl (NHC-2), and adamantyl-isopropyl (NHC-3) benzimidazolium salts react with palladium(II) bromide in pyridine to afford the corresponding trans-dibromidopyridinepalladium(II) complexes Pd-C1, Pd-C2, and Pd-C3 in high yields. A d...

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Detalles Bibliográficos
Autores principales: Mansour, Waseem, Suleiman, Rami, Fettouhi, Mohammed, El Ali, Bassam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7513372/
https://www.ncbi.nlm.nih.gov/pubmed/32984688
http://dx.doi.org/10.1021/acsomega.0c02413

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