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Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only
Based on the foundations of thermodynamics and the equilibrium conditions for the coexistence of two phases in a magnetic Ising-like system, we show, first, that there is a critical point where the isothermal susceptibility diverges and the specific heat may remain finite, and second, that near the...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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MDPI
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7516989/ https://www.ncbi.nlm.nih.gov/pubmed/33286275 http://dx.doi.org/10.3390/e22050502 |
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author | Romero-Rochín, Víctor |
author_facet | Romero-Rochín, Víctor |
author_sort | Romero-Rochín, Víctor |
collection | PubMed |
description | Based on the foundations of thermodynamics and the equilibrium conditions for the coexistence of two phases in a magnetic Ising-like system, we show, first, that there is a critical point where the isothermal susceptibility diverges and the specific heat may remain finite, and second, that near the critical point the entropy of the system, and therefore all free energies, do obey scaling. Although we limit ourselves to such a system, we elaborate about the possibilities of finding universality, as well as the precise values of the critical exponents using thermodynamics only. |
format | Online Article Text |
id | pubmed-7516989 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-75169892020-11-09 Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only Romero-Rochín, Víctor Entropy (Basel) Article Based on the foundations of thermodynamics and the equilibrium conditions for the coexistence of two phases in a magnetic Ising-like system, we show, first, that there is a critical point where the isothermal susceptibility diverges and the specific heat may remain finite, and second, that near the critical point the entropy of the system, and therefore all free energies, do obey scaling. Although we limit ourselves to such a system, we elaborate about the possibilities of finding universality, as well as the precise values of the critical exponents using thermodynamics only. MDPI 2020-04-27 /pmc/articles/PMC7516989/ /pubmed/33286275 http://dx.doi.org/10.3390/e22050502 Text en © 2020 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Romero-Rochín, Víctor Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only |
title | Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only |
title_full | Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only |
title_fullStr | Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only |
title_full_unstemmed | Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only |
title_short | Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only |
title_sort | derivation of the critical point scaling hypothesis using thermodynamics only |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7516989/ https://www.ncbi.nlm.nih.gov/pubmed/33286275 http://dx.doi.org/10.3390/e22050502 |
work_keys_str_mv | AT romerorochinvictor derivationofthecriticalpointscalinghypothesisusingthermodynamicsonly |