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Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only

Based on the foundations of thermodynamics and the equilibrium conditions for the coexistence of two phases in a magnetic Ising-like system, we show, first, that there is a critical point where the isothermal susceptibility diverges and the specific heat may remain finite, and second, that near the...

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Autor principal: Romero-Rochín, Víctor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7516989/
https://www.ncbi.nlm.nih.gov/pubmed/33286275
http://dx.doi.org/10.3390/e22050502
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author Romero-Rochín, Víctor
author_facet Romero-Rochín, Víctor
author_sort Romero-Rochín, Víctor
collection PubMed
description Based on the foundations of thermodynamics and the equilibrium conditions for the coexistence of two phases in a magnetic Ising-like system, we show, first, that there is a critical point where the isothermal susceptibility diverges and the specific heat may remain finite, and second, that near the critical point the entropy of the system, and therefore all free energies, do obey scaling. Although we limit ourselves to such a system, we elaborate about the possibilities of finding universality, as well as the precise values of the critical exponents using thermodynamics only.
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spelling pubmed-75169892020-11-09 Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only Romero-Rochín, Víctor Entropy (Basel) Article Based on the foundations of thermodynamics and the equilibrium conditions for the coexistence of two phases in a magnetic Ising-like system, we show, first, that there is a critical point where the isothermal susceptibility diverges and the specific heat may remain finite, and second, that near the critical point the entropy of the system, and therefore all free energies, do obey scaling. Although we limit ourselves to such a system, we elaborate about the possibilities of finding universality, as well as the precise values of the critical exponents using thermodynamics only. MDPI 2020-04-27 /pmc/articles/PMC7516989/ /pubmed/33286275 http://dx.doi.org/10.3390/e22050502 Text en © 2020 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Romero-Rochín, Víctor
Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only
title Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only
title_full Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only
title_fullStr Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only
title_full_unstemmed Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only
title_short Derivation of the Critical Point Scaling Hypothesis Using Thermodynamics Only
title_sort derivation of the critical point scaling hypothesis using thermodynamics only
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7516989/
https://www.ncbi.nlm.nih.gov/pubmed/33286275
http://dx.doi.org/10.3390/e22050502
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