Cargando…
Agar-entrapped sulfonated DABCO: Agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives
In this project, a recently synthesized DABCO-based catalyst is entrapped in agar to reduce its moisture sensitivity leading to enhancement of its stability and catalytic activity. After preparation and identification this new reagent is used as an efficient and environmentally safe catalyst for the...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier B.V.
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7518970/ https://www.ncbi.nlm.nih.gov/pubmed/33012844 http://dx.doi.org/10.1016/j.molstruc.2020.129336 |
_version_ | 1783587482204372992 |
---|---|
author | Moghaddampour, Issa Mousazadeh Shirini, Farhad Langarudi, Mohaddeseh Safarpoor Nikoo |
author_facet | Moghaddampour, Issa Mousazadeh Shirini, Farhad Langarudi, Mohaddeseh Safarpoor Nikoo |
author_sort | Moghaddampour, Issa Mousazadeh |
collection | PubMed |
description | In this project, a recently synthesized DABCO-based catalyst is entrapped in agar to reduce its moisture sensitivity leading to enhancement of its stability and catalytic activity. After preparation and identification this new reagent is used as an efficient and environmentally safe catalyst for the preparation of 1, 2, 4-triazoloquinazolinone and some pyrimidine derivatives. This method is accompanied with some superiorities such as, simple operation, mild and green conditions, use of low cost and non-hazardous natural material, short reaction times, easy preparation methods and simple work-up procedures. The prepared catalyst can be re-used for several times in all of the studied reactions without any appreciable loss in its activity. |
format | Online Article Text |
id | pubmed-7518970 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | Elsevier B.V. |
record_format | MEDLINE/PubMed |
spelling | pubmed-75189702020-09-28 Agar-entrapped sulfonated DABCO: Agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives Moghaddampour, Issa Mousazadeh Shirini, Farhad Langarudi, Mohaddeseh Safarpoor Nikoo J Mol Struct Article In this project, a recently synthesized DABCO-based catalyst is entrapped in agar to reduce its moisture sensitivity leading to enhancement of its stability and catalytic activity. After preparation and identification this new reagent is used as an efficient and environmentally safe catalyst for the preparation of 1, 2, 4-triazoloquinazolinone and some pyrimidine derivatives. This method is accompanied with some superiorities such as, simple operation, mild and green conditions, use of low cost and non-hazardous natural material, short reaction times, easy preparation methods and simple work-up procedures. The prepared catalyst can be re-used for several times in all of the studied reactions without any appreciable loss in its activity. Elsevier B.V. 2021-02-15 2020-09-26 /pmc/articles/PMC7518970/ /pubmed/33012844 http://dx.doi.org/10.1016/j.molstruc.2020.129336 Text en © 2020 Elsevier B.V. All rights reserved. Since January 2020 Elsevier has created a COVID-19 resource centre with free information in English and Mandarin on the novel coronavirus COVID-19. The COVID-19 resource centre is hosted on Elsevier Connect, the company's public news and information website. Elsevier hereby grants permission to make all its COVID-19-related research that is available on the COVID-19 resource centre - including this research content - immediately available in PubMed Central and other publicly funded repositories, such as the WHO COVID database with rights for unrestricted research re-use and analyses in any form or by any means with acknowledgement of the original source. These permissions are granted for free by Elsevier for as long as the COVID-19 resource centre remains active. |
spellingShingle | Article Moghaddampour, Issa Mousazadeh Shirini, Farhad Langarudi, Mohaddeseh Safarpoor Nikoo Agar-entrapped sulfonated DABCO: Agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives |
title | Agar-entrapped sulfonated DABCO: Agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives |
title_full | Agar-entrapped sulfonated DABCO: Agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives |
title_fullStr | Agar-entrapped sulfonated DABCO: Agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives |
title_full_unstemmed | Agar-entrapped sulfonated DABCO: Agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives |
title_short | Agar-entrapped sulfonated DABCO: Agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives |
title_sort | agar-entrapped sulfonated dabco: agelly acidic catalyst for the acceleration of one-pot synthesis of 1,2,4-triazoloquinazolinone and some pyrimidine derivatives |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7518970/ https://www.ncbi.nlm.nih.gov/pubmed/33012844 http://dx.doi.org/10.1016/j.molstruc.2020.129336 |
work_keys_str_mv | AT moghaddampourissamousazadeh agarentrappedsulfonateddabcoagellyacidiccatalystfortheaccelerationofonepotsynthesisof124triazoloquinazolinoneandsomepyrimidinederivatives AT shirinifarhad agarentrappedsulfonateddabcoagellyacidiccatalystfortheaccelerationofonepotsynthesisof124triazoloquinazolinoneandsomepyrimidinederivatives AT langarudimohaddesehsafarpoornikoo agarentrappedsulfonateddabcoagellyacidiccatalystfortheaccelerationofonepotsynthesisof124triazoloquinazolinoneandsomepyrimidinederivatives |