Cargando…

Crystal structure and Hirshfeld surface analysis of (E)-N-(4-propyl­oxybenzyl­idene)benzo[d]thia­zol-2-amine

The title compound, C(17)H(16)N(2)OS, was synthesized by a condensation reaction between 2-amino benzo­thia­zole and 4-N-propoxybenzaldehyde. The benzo[d]thia­zole ring system is nearly planar (r.m.s. deviation 0.0088 Å) and makes a dihedral angle of 3.804 (12)° with the phenyl ring. The configurati...

Descripción completa

Detalles Bibliográficos
Autores principales: Sheakh Mohamad, Ropak A., Hamad, Wali M., Aziz, Hashim J., Dege, Necmi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7534222/
https://www.ncbi.nlm.nih.gov/pubmed/33117570
http://dx.doi.org/10.1107/S2056989020012128
Descripción
Sumario:The title compound, C(17)H(16)N(2)OS, was synthesized by a condensation reaction between 2-amino benzo­thia­zole and 4-N-propoxybenzaldehyde. The benzo[d]thia­zole ring system is nearly planar (r.m.s. deviation 0.0088 Å) and makes a dihedral angle of 3.804 (12)° with the phenyl ring. The configuration about the C=N double bond is E. In the crystal structure, pairs of C—H⋯N hydrogen bonds and C—H⋯π inter­actions link the mol­ecules into inversion dimers with an R (2) (2)(16) ring motif. These dimers are additionally linked by weak π–π stacking inter­actions between the phenyl rings, leading to a layered arrangement parallel to (010). Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the packing arrangement are from H⋯H (47.9%) and C⋯H/H⋯C (25.6%) inter­actions.