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Crystal structure of bis­{μ-2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato}bis­(μ-3,5-di­methyl­pyrazolato)tricopper(II) dibromide sesquihydrate

In the title bicyclic trinuclear pyrazolate amino­alcohol complex, [Cu(3)(C(5)H(7)N(2))(2)(C(6)H(14)NO(3))(2)]Br(2)·1.5H(2)O, the central Cu atom lies on a center of symmetry and is involved in the formation of two five-membered rings. It has a coordination number of 4, is in a distorted tetra­hedra...

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Detalles Bibliográficos
Autores principales: Vynohradov, Oleksandr S., Pavlenko, Vadim A., Naumova, Dina D., Partsevska, Sofiia V., Shova, Sergiu, Safarmamadov, Safarmamad M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7534225/
https://www.ncbi.nlm.nih.gov/pubmed/33117580
http://dx.doi.org/10.1107/S2056989020012323
Descripción
Sumario:In the title bicyclic trinuclear pyrazolate amino­alcohol complex, [Cu(3)(C(5)H(7)N(2))(2)(C(6)H(14)NO(3))(2)]Br(2)·1.5H(2)O, the central Cu atom lies on a center of symmetry and is involved in the formation of two five-membered rings. It has a coordination number of 4, is in a distorted tetra­hedral environment and is connected by the bridging oxygen atoms of the deprotonated OH groups of different amino­alcohol groups, and by the N atoms of deprotonated di­methyl­pyrazole ligands. The peripheral Cu atom is in a trigonal–bipyramidal coordination environment formed by the nitro­gen atom of the deprotonated bridging di­methyl­pyrazole unit, the bridging oxygen atom of the deprotonated OH group, two oxygen atoms of the protonated hy­droxy groups and the nitro­gen atom of tri­ethano­lamine. One of the C atoms and the Br(−) anion were found to be disordered over two positions with occupancy factors of 0.808 (9):0.192 (9) and 0.922 (3):0.078 (3), respectively.