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Crystal structures of three functionalized chalcones: 4′-di­methyl­amino-3-nitro­chalcone, 3-di­methyl­amino-3′-nitrochalcone and 3′-nitro­chalcone

The structure of three functionalized chalcones (1,3-di­aryl­prop-2-en-1-ones), containing combinations of nitro and di­methyl­amino functional groups, are presented, namely, 1-[4-(di­methyl­amino)­phen­yl]-3-(3-nitro­phen­yl)prop-2-en-1-one, C(17)H(16)N(2)O(3), Gp8m, 3-[3-(di­methyl­amino)­phen­yl]...

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Detalles Bibliográficos
Autores principales: Hall, Charlie L., Hamilton, Victoria, Potticary, Jason, Cremeens, Matthew E., Pridmore, Natalie E., Sparkes, Hazel A., D’ambruoso, Gemma D., Warren, Stephen D., Matsumoto, Masaomi, Hall, Simon R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7534226/
https://www.ncbi.nlm.nih.gov/pubmed/33117572
http://dx.doi.org/10.1107/S2056989020011858
Descripción
Sumario:The structure of three functionalized chalcones (1,3-di­aryl­prop-2-en-1-ones), containing combinations of nitro and di­methyl­amino functional groups, are presented, namely, 1-[4-(di­methyl­amino)­phen­yl]-3-(3-nitro­phen­yl)prop-2-en-1-one, C(17)H(16)N(2)O(3), Gp8m, 3-[3-(di­methyl­amino)­phen­yl]-1-(3-nitro­phen­yl)prop-2-en-1-one, C(17)H(16)N(2)O(3), Hm7m and 1-(3-nitro­phen­yl)-3-phenyl­prop-2-en-1-one, C(15)H(11)NO(3), Hm1-. Each of the mol­ecules contains bonding motifs seen in previously solved crystal structures of functionalized chalcones, adding to the large dataset available for these small organic mol­ecules. The structures of all three of the title compounds contain similar bonding motifs, resulting in two-dimensional planes of mol­ecules formed via C—H⋯O hydrogen-bonding inter­actions involving the nitro- and ketone groups. The structure of Hm1- is very similar to the crystal structure of a previously solved isomer [Jing (2009 ▸). Acta Cryst. E65, o2510].