Determination of Mercury Content in Surface Waters Using an Environmentally Non-Toxic Terminating Electrolyte

The paper presents results of the research on the dynamics of changes in the concentration of mercury in surface waters. The importance of mercury as an environmental pollutant results from specific properties of this metal, many sources of contamination, volatility, mobility, stability and high toxicity of its specific chemical forms. Samples of surface water collected from three rivers: the Bug, the Liwiec and the Muchawka were analysed. The Muchawka River flows into the Liwiec River, which in turn is a tributary of the Bug River. The technique of isotachophoresis was employed, using a solution of a biodegradable and environmentally non-toxic derivative of electrostatically stabilised silanates as the terminating electrolyte. The highest average mercury concentration of 0.89 μg/dm(3) was determined in water samples collected from the Bug River in January, whereas the lowest concentration of 0.42 μg/dm(3) was recorded in water collected from the Muchawka River in September.