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ZnO–Ti(3)C(2) MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes

2D transition metal carbides, nitrides, and carbonitrides called MXenes show outstanding performance in many applications due to their superior physical and chemical properties. Herein, a ZnO–MXene mixture with different contents of Ti(3)C(2) is applied as electron transport layers (ETLs) and the in...

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Autores principales: Lu, Po, Wu, Jinlei, Shen, Xinyu, Gao, Xupeng, Shi, Zhifeng, Lu, Min, Yu, William W., Zhang, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7539190/
https://www.ncbi.nlm.nih.gov/pubmed/35403379
http://dx.doi.org/10.1002/advs.202001562
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author Lu, Po
Wu, Jinlei
Shen, Xinyu
Gao, Xupeng
Shi, Zhifeng
Lu, Min
Yu, William W.
Zhang, Yu
author_facet Lu, Po
Wu, Jinlei
Shen, Xinyu
Gao, Xupeng
Shi, Zhifeng
Lu, Min
Yu, William W.
Zhang, Yu
author_sort Lu, Po
collection PubMed
description 2D transition metal carbides, nitrides, and carbonitrides called MXenes show outstanding performance in many applications due to their superior physical and chemical properties. Herein, a ZnO–MXene mixture with different contents of Ti(3)C(2) is applied as electron transport layers (ETLs) and the influence of the Ti(3)C(2) MXene in all‐inorganic metal halide perovskite nanocrystal light‐emitting diodes (perovskite NC LEDs) is explored. The addition of Ti(3)C(2) makes more balanced charge carrier transport in LEDs by changing the energy level structure and electron mobility of ETL. Moreover, lower surface roughness is obtained for the ETL, thus guaranteeing uniform distribution of the perovskite NCs layer and further reducing leakage current. As a result, a 17.4% external quantum efficiency (EQE) with low efficiency roll‐off is achieved with 10% Ti(3)C(2), which is a 22.5% improvement compared to LEDs without Ti(3)C(2).
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spelling pubmed-75391902020-10-09 ZnO–Ti(3)C(2) MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes Lu, Po Wu, Jinlei Shen, Xinyu Gao, Xupeng Shi, Zhifeng Lu, Min Yu, William W. Zhang, Yu Adv Sci (Weinh) Communications 2D transition metal carbides, nitrides, and carbonitrides called MXenes show outstanding performance in many applications due to their superior physical and chemical properties. Herein, a ZnO–MXene mixture with different contents of Ti(3)C(2) is applied as electron transport layers (ETLs) and the influence of the Ti(3)C(2) MXene in all‐inorganic metal halide perovskite nanocrystal light‐emitting diodes (perovskite NC LEDs) is explored. The addition of Ti(3)C(2) makes more balanced charge carrier transport in LEDs by changing the energy level structure and electron mobility of ETL. Moreover, lower surface roughness is obtained for the ETL, thus guaranteeing uniform distribution of the perovskite NCs layer and further reducing leakage current. As a result, a 17.4% external quantum efficiency (EQE) with low efficiency roll‐off is achieved with 10% Ti(3)C(2), which is a 22.5% improvement compared to LEDs without Ti(3)C(2). John Wiley and Sons Inc. 2020-08-16 /pmc/articles/PMC7539190/ /pubmed/35403379 http://dx.doi.org/10.1002/advs.202001562 Text en © 2020 The Authors. Published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Lu, Po
Wu, Jinlei
Shen, Xinyu
Gao, Xupeng
Shi, Zhifeng
Lu, Min
Yu, William W.
Zhang, Yu
ZnO–Ti(3)C(2) MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes
title ZnO–Ti(3)C(2) MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes
title_full ZnO–Ti(3)C(2) MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes
title_fullStr ZnO–Ti(3)C(2) MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes
title_full_unstemmed ZnO–Ti(3)C(2) MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes
title_short ZnO–Ti(3)C(2) MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes
title_sort zno–ti(3)c(2) mxene electron transport layer for high external quantum efficiency perovskite nanocrystal light‐emitting diodes
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7539190/
https://www.ncbi.nlm.nih.gov/pubmed/35403379
http://dx.doi.org/10.1002/advs.202001562
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