Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer

The challenge of quantitatively forming self‐assembled heterodimers without other equilibrium by‐products is overcome through self‐sorting favored by the introduction of designed shape‐complementary moieties. Such a supramolecular strategy based on cucurbit[8]uril‐directed dimerization is further ap...

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Detalles Bibliográficos
Autores principales: Wu, Guanglu, Huang, Zehuan, Scherman, Oren A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540262/
https://www.ncbi.nlm.nih.gov/pubmed/32495447
http://dx.doi.org/10.1002/anie.202006530
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author Wu, Guanglu
Huang, Zehuan
Scherman, Oren A.
author_facet Wu, Guanglu
Huang, Zehuan
Scherman, Oren A.
author_sort Wu, Guanglu
collection PubMed
description The challenge of quantitatively forming self‐assembled heterodimers without other equilibrium by‐products is overcome through self‐sorting favored by the introduction of designed shape‐complementary moieties. Such a supramolecular strategy based on cucurbit[8]uril‐directed dimerization is further applied to generate hetero‐chromophore dimers quantitatively, leading to efficient energy transfer (>85 %) upon photoexcitation.
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spelling pubmed-75402622020-10-09 Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer Wu, Guanglu Huang, Zehuan Scherman, Oren A. Angew Chem Int Ed Engl Communications The challenge of quantitatively forming self‐assembled heterodimers without other equilibrium by‐products is overcome through self‐sorting favored by the introduction of designed shape‐complementary moieties. Such a supramolecular strategy based on cucurbit[8]uril‐directed dimerization is further applied to generate hetero‐chromophore dimers quantitatively, leading to efficient energy transfer (>85 %) upon photoexcitation. John Wiley and Sons Inc. 2020-07-13 2020-09-07 /pmc/articles/PMC7540262/ /pubmed/32495447 http://dx.doi.org/10.1002/anie.202006530 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Wu, Guanglu
Huang, Zehuan
Scherman, Oren A.
Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer
title Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer
title_full Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer
title_fullStr Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer
title_full_unstemmed Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer
title_short Quantitative Supramolecular Heterodimerization for Efficient Energy Transfer
title_sort quantitative supramolecular heterodimerization for efficient energy transfer
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540262/
https://www.ncbi.nlm.nih.gov/pubmed/32495447
http://dx.doi.org/10.1002/anie.202006530
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AT huangzehuan quantitativesupramolecularheterodimerizationforefficientenergytransfer
AT schermanorena quantitativesupramolecularheterodimerizationforefficientenergytransfer

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