S(6)N(2)O(15)—A Nitrogen‐Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido‐tris‐Sulfuric Acid

The reaction of hexachlorophosphazene, P(3)N(3)Cl(6), with SO(3) leads to the new sulfur nitride oxide S(6)N(2)O(15). The compound displays an extraordinarily low nitrogen content and exhibits a bicyclic cage structure according to the formulation N{S(O)(2)O(O)(2)S}(3)N, with both nitrogen atoms in...

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Detalles Bibliográficos
Autores principales: van Gerven, David, Wickleder, Mathias S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540367/
https://www.ncbi.nlm.nih.gov/pubmed/32648319
http://dx.doi.org/10.1002/anie.202005056
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author van Gerven, David
Wickleder, Mathias S.
author_facet van Gerven, David
Wickleder, Mathias S.
author_sort van Gerven, David
collection PubMed
description The reaction of hexachlorophosphazene, P(3)N(3)Cl(6), with SO(3) leads to the new sulfur nitride oxide S(6)N(2)O(15). The compound displays an extraordinarily low nitrogen content and exhibits a bicyclic cage structure according to the formulation N{S(O)(2)O(O)(2)S}(3)N, with both nitrogen atoms in trigonal planar coordination of sulfur atoms. Interestingly, the new nitride oxide can be also seen as the anhydride of nitrido‐tris‐sulfuric acid, N(SO(3)H)(3).
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spelling pubmed-75403672020-10-09 S(6)N(2)O(15)—A Nitrogen‐Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido‐tris‐Sulfuric Acid van Gerven, David Wickleder, Mathias S. Angew Chem Int Ed Engl Communications The reaction of hexachlorophosphazene, P(3)N(3)Cl(6), with SO(3) leads to the new sulfur nitride oxide S(6)N(2)O(15). The compound displays an extraordinarily low nitrogen content and exhibits a bicyclic cage structure according to the formulation N{S(O)(2)O(O)(2)S}(3)N, with both nitrogen atoms in trigonal planar coordination of sulfur atoms. Interestingly, the new nitride oxide can be also seen as the anhydride of nitrido‐tris‐sulfuric acid, N(SO(3)H)(3). John Wiley and Sons Inc. 2020-08-04 2020-09-21 /pmc/articles/PMC7540367/ /pubmed/32648319 http://dx.doi.org/10.1002/anie.202005056 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
van Gerven, David
Wickleder, Mathias S.
S(6)N(2)O(15)—A Nitrogen‐Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido‐tris‐Sulfuric Acid
title S(6)N(2)O(15)—A Nitrogen‐Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido‐tris‐Sulfuric Acid
title_full S(6)N(2)O(15)—A Nitrogen‐Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido‐tris‐Sulfuric Acid
title_fullStr S(6)N(2)O(15)—A Nitrogen‐Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido‐tris‐Sulfuric Acid
title_full_unstemmed S(6)N(2)O(15)—A Nitrogen‐Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido‐tris‐Sulfuric Acid
title_short S(6)N(2)O(15)—A Nitrogen‐Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido‐tris‐Sulfuric Acid
title_sort s(6)n(2)o(15)—a nitrogen‐poor sulfur nitride oxide, and the anhydride of nitrido‐tris‐sulfuric acid
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540367/
https://www.ncbi.nlm.nih.gov/pubmed/32648319
http://dx.doi.org/10.1002/anie.202005056
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