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Cyclopropenylmethyl Cation: A Concealed Intermediate in Gold(I)‐Catalyzed Reactions

The last years have witnessed many gold‐catalyzed reactions of alkynes. One of the most prominent species in the reaction of two alkyne units is the vinyl‐substituted gold vinylidene intermediate. Here, we were able to show that the reaction of a haloacetylene and an alkyne proceeds via a hitherto o...

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Detalles Bibliográficos
Autores principales: Kreuzahler, Mathis, Haberhauer, Gebhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540476/
https://www.ncbi.nlm.nih.gov/pubmed/32515893
http://dx.doi.org/10.1002/anie.202006245

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