Cargando…

Trifluoromethyl Sulfoxides: Reagents for Metal‐Free C−H Trifluoromethylthiolation

Trifluoromethyl sulfoxides are a new class of trifluoromethylthiolating reagent. The sulfoxides engage in metal‐free C−H trifluoromethylthiolation with a range of (hetero)arenes. The method is also applicable to the functionalization of important compound classes, such as ligand derivatives and poly...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Dong, Carlton, C. Grace, Tayu, Masanori, McDouall, Joseph J. W., Perry, Gregory J. P., Procter, David J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540508/ https://www.ncbi.nlm.nih.gov/pubmed/32463942 http://dx.doi.org/10.1002/anie.202005531

Ejemplares similares

One pot synthesis of trifluoromethyl aryl sulfoxides by trifluoromethylthiolation of arenes and subsequent oxidation with hydrogen peroxide
por: Horvat, Monika, et al.
Publicado: (2020)

Trifluoromethylthiolation, Trifluoromethylation, and Arylation Reactions of Difluoro Enol Silyl Ethers
por: Jiang, Xingguo, et al.
Publicado: (2020)

Metal-Free Trifluoromethylthiolation of Arylazo Sulfones
por: Li, Ankun, et al.
Publicado: (2020)

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions
por: Yang, Xiaoyu, et al.
Publicado: (2014)

Copper‐Catalyzed Borylative Cross‐Coupling of Allenes and Imines: Selective Three‐Component Assembly of Branched Homoallyl Amines
por: Rae, James, et al.
Publicado: (2015)

Sulfoxide-Directed Metal-Free ortho-Propargylation of Aromatics and Heteroaromatics
por: Eberhart, Andrew J, et al.
Publicado: (2015)

Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation
por: Luo, Jie, et al.
Publicado: (2018)

SmI(2)-Catalyzed Intermolecular Coupling of Cyclopropyl Ketones and Alkynes: A Link between Ketone Conformation and Reactivity
por: Agasti, Soumitra, et al.
Publicado: (2021)

Catalytic trifluoromethylation of iodoarenes by use of 2-trifluoromethylated benzimidazoline as trifluoromethylating reagent
por: Uchikura, Tatsuhiro, et al.
Publicado: (2020)

Decarboxylative trifluoromethylthiolation of pyridylacetates
por: Kawanishi, Ryouta, et al.
Publicado: (2021)

Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagent
por: Wang, Xiao-Ping, et al.
Publicado: (2013)

Sulfoxide-mediated oxidative cross-coupling of phenols
por: He, Zhen, et al.
Publicado: (2020)

2‐Diazo‐1‐phenyl‐2‐((trifluoromethyl)sulfonyl)ethan‐1‐one: Another Utility for Electrophilic Trifluoromethylthiolation Reactions
por: Huang, Zhongyan, et al.
Publicado: (2016)

Late-stage trifluoromethylthiolation of benzylic C-H bonds
por: Xu, Wentao, et al.
Publicado: (2019)

Deoxygenative trifluoromethylthiolation of carboxylic acids
por: Mao, Runze, et al.
Publicado: (2019)

Recent advances in transition metal-catalyzed Csp(2)-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation
por: Landelle, Grégory, et al.
Publicado: (2013)

A Sulfoxide Reagent for One‐Pot, Three‐Component Syntheses of Sulfoxides and Sulfinamides
por: Saito, Fumito
Publicado: (2022)

Sulfoxide-directed metal-free cross-couplings in the expedient synthesis of benzothiophene-based components of materials
por: Eberhart, Andrew J., et al.
Publicado: (2016)

Synthesis of trifluoromethylated 2H-azirines through Togni reagent-mediated trifluoromethylation followed by PhIO-mediated azirination
por: Sun, Jiyun, et al.
Publicado: (2018)

Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent
por: Egami, Hiromichi, et al.
Publicado: (2015)

Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide
por: Alazet, Sébastien, et al.
Publicado: (2013)

Chemoselective α-Sulfidation of Amides Using Sulfoxide Reagents
por: Leypold, Mario, et al.
Publicado: (2020)

Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide
por: Nakamura, Yuzo, et al.
Publicado: (2013)

Peri-operative fluid management in major colorectal surgery: do we comply with current guidance and what are the implications for our patients?
por: Vincent, L, et al.
Publicado: (2015)

Trifluoromethylthiolation–arylation of diazocarbonyl compounds by modified Hooz multicomponent coupling
por: Lübcke, Marvin, et al.
Publicado: (2019)

Deoxyfluorination of acyl fluorides to trifluoromethyl compounds by FLUOLEAD(®)/Olah’s reagent under solvent-free conditions
por: Liang, Yumeng, et al.
Publicado: (2020)

Nickel-catalyzed trifluoromethylthiolation of Csp(2)–O bonds
por: Dürr, Alexander B., et al.
Publicado: (2016)

Direct heterobenzylic fluorination, difluorination and trifluoromethylthiolation with dibenzenesulfonamide derivatives
por: Meanwell, Michael, et al.
Publicado: (2018)

Survive and thrive wellbeing programme: an innovative experiential wellbeing programme for trainees in Health Education England- Thames Valley (HEE-TV)
por: Vlachos, Haido, et al.
Publicado: (2021)

Insight into trifluoromethylation – experimental electron density for Togni reagent I
por: Wang, R., et al.
Publicado: (2018)

Graphene oxide-catalyzed trifluoromethylation of alkynes with quinoxalinones and Langlois' reagent
por: Li, Hong, et al.
Publicado: (2021)

Trifluoromethylthiolation of Tryptophan and Tyrosine Derivatives: A Tool for Enhancing the Local Hydrophobicity of Peptides
por: Gregorc, Jure, et al.
Publicado: (2023)

Metal-Free Trifluoromethylation of Aromatic and Heteroaromatic Aldehydes and Ketones
por: Qiao, Yupu, et al.
Publicado: (2014)

Metal‐Free N−H Bond Activation by Phospha‐Wittig Reagents
por: Dankert, Fabian, et al.
Publicado: (2022)

Bismuth(III)-Promoted Trifluoromethylthiolation of Pyrazolin-5-ones with Trifluoromethanesulfenamide
por: Liu, Qingyun, et al.
Publicado: (2017)

Cascade trifluoromethylthiolation and cyclization of N-[(3-aryl)propioloyl]indoles
por: Bi, Ming-Xi, et al.
Publicado: (2020)

Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective
por: Shibata, Norio, et al.
Publicado: (2010)

Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF(3)(+), CF(3)(•), and CF(3)(–) Reactivity
por: Jia, Hao, et al.
Publicado: (2021)

Recent advances in intermolecular 1,2-difunctionalization of alkenes involving trifluoromethylthiolation
por: Yan-mei, Li, et al.
Publicado: (2021)

Comparative profiling of well-defined copper reagents and precursors for the trifluoromethylation of aryl iodides
por: Kaplan, Peter T, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_ufjcj2ke3jcg38qqhvp5dvqbob