Boosting Low‐Valent Aluminum(I) Reactivity with a Potassium Reagent

The reagent RK [R=CH(SiMe(3))(2) or N(SiMe(3))(2)] was expected to react with the low‐valent ((DIPP)BDI)Al ((DIPP)BDI=HC[C(Me)N(DIPP)](2), DIPP=2,6‐iPr‐phenyl) to give [((DIPP)BDI)AlR](−)K(+). However, deprotonation of the Me group in the ligand backbone was observed and [H(2)C=C(N‐DIPP)−C(H)=C(Me)−...

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Detalles Bibliográficos
Autores principales: Grams, Samuel, Eyselein, Jonathan, Langer, Jens, Färber, Christian, Harder, Sjoerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540686/
https://www.ncbi.nlm.nih.gov/pubmed/32449816
http://dx.doi.org/10.1002/anie.202006693

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540686/
https://www.ncbi.nlm.nih.gov/pubmed/32449816
http://dx.doi.org/10.1002/anie.202006693

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