Cargando…
Boosting Low‐Valent Aluminum(I) Reactivity with a Potassium Reagent
The reagent RK [R=CH(SiMe(3))(2) or N(SiMe(3))(2)] was expected to react with the low‐valent ((DIPP)BDI)Al ((DIPP)BDI=HC[C(Me)N(DIPP)](2), DIPP=2,6‐iPr‐phenyl) to give [((DIPP)BDI)AlR](−)K(+). However, deprotonation of the Me group in the ligand backbone was observed and [H(2)C=C(N‐DIPP)−C(H)=C(Me)−...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7540686/ https://www.ncbi.nlm.nih.gov/pubmed/32449816 http://dx.doi.org/10.1002/anie.202006693 |