Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles

A single pot, wet chemical route has been applied for the synthesis of polymer supported copper azide, CuN(3), nanoparticles (CANP). The hybrid system was used as ‘catalyst-cum-reagent’ for the azide-alkyne cyclo-addition reaction to construct triazole molecules using substituted benzyl bromide and...

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Autores principales: Nandi, Debkumar, Perla, Venkata K., Ghosh, Sarit K., Arderne, Charmaine, Mallick, Kaushik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7542177/
https://www.ncbi.nlm.nih.gov/pubmed/33028925
http://dx.doi.org/10.1038/s41598-020-74018-8
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author Nandi, Debkumar
Perla, Venkata K.
Ghosh, Sarit K.
Arderne, Charmaine
Mallick, Kaushik
author_facet Nandi, Debkumar
Perla, Venkata K.
Ghosh, Sarit K.
Arderne, Charmaine
Mallick, Kaushik
author_sort Nandi, Debkumar
collection PubMed
description A single pot, wet chemical route has been applied for the synthesis of polymer supported copper azide, CuN(3), nanoparticles (CANP). The hybrid system was used as ‘catalyst-cum-reagent’ for the azide-alkyne cyclo-addition reaction to construct triazole molecules using substituted benzyl bromide and terminal alkyne. The electron donating group containing terminal alkyne produced 5-alkynyl 1,4-disubstituded triazole product whereas for alkyne molecule with terminal electron withdrawing group facilitate the formation of 1,4-disubstituted triazole molecule.
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spelling pubmed-75421772020-10-08 Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles Nandi, Debkumar Perla, Venkata K. Ghosh, Sarit K. Arderne, Charmaine Mallick, Kaushik Sci Rep Article A single pot, wet chemical route has been applied for the synthesis of polymer supported copper azide, CuN(3), nanoparticles (CANP). The hybrid system was used as ‘catalyst-cum-reagent’ for the azide-alkyne cyclo-addition reaction to construct triazole molecules using substituted benzyl bromide and terminal alkyne. The electron donating group containing terminal alkyne produced 5-alkynyl 1,4-disubstituded triazole product whereas for alkyne molecule with terminal electron withdrawing group facilitate the formation of 1,4-disubstituted triazole molecule. Nature Publishing Group UK 2020-10-07 /pmc/articles/PMC7542177/ /pubmed/33028925 http://dx.doi.org/10.1038/s41598-020-74018-8 Text en © The Author(s) 2020 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Nandi, Debkumar
Perla, Venkata K.
Ghosh, Sarit K.
Arderne, Charmaine
Mallick, Kaushik
Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_full Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_fullStr Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_full_unstemmed Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_short Copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
title_sort copper-azide nanoparticle: a ‘catalyst-cum-reagent’ for the designing of 5-alkynyl 1,4-disubstituted triazoles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7542177/
https://www.ncbi.nlm.nih.gov/pubmed/33028925
http://dx.doi.org/10.1038/s41598-020-74018-8
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