The key role of R–NHC coupling (R = C, H, heteroatom) and M–NHC bond cleavage in the evolution of M/NHC complexes and formation of catalytically active species

Complexes of metals with N-heterocyclic carbene ligands (M/NHC) are typically considered the systems of choice in homogeneous catalysis due to their stable metal–ligand framework. However, it becomes obvious that even metal species with a strong M–NHC bond can undergo evolution in catalytic systems,...

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Detalles Bibliográficos
Autores principales: Chernyshev, Victor M., Denisova, Ekaterina A., Eremin, Dmitry B., Ananikov, Valentine P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7553045/
https://www.ncbi.nlm.nih.gov/pubmed/33133486
http://dx.doi.org/10.1039/d0sc02629h

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