One-Pot Parallel Synthesis of Unclosed Cryptands—Searching for Selective Anion Receptors via Static Combinatorial Chemistry Techniques

[Image: see text] We present the synthesis of 17 macrocyclic compounds having the structure of so-called unclosed cryptands, acting as anion receptors. These compounds possess amide functions playing the role of hydrogen-bond-donating systems. We have synthesized the presented compounds both by stan...

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Autores principales: Niedbała, Patryk, Jurczak, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7558039/
https://www.ncbi.nlm.nih.gov/pubmed/33073154
http://dx.doi.org/10.1021/acsomega.0c04228
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author Niedbała, Patryk
Jurczak, Janusz
author_facet Niedbała, Patryk
Jurczak, Janusz
author_sort Niedbała, Patryk
collection PubMed
description [Image: see text] We present the synthesis of 17 macrocyclic compounds having the structure of so-called unclosed cryptands, acting as anion receptors. These compounds possess amide functions playing the role of hydrogen-bond-donating systems. We have synthesized the presented compounds both by standard methods (using batch conditions) and by static combinatorial chemistry methods, using tetrabutylammonium dihydrogen phosphate as a template, promoting the lariat arm postfunctionalization reaction.
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spelling pubmed-75580392020-10-16 One-Pot Parallel Synthesis of Unclosed Cryptands—Searching for Selective Anion Receptors via Static Combinatorial Chemistry Techniques Niedbała, Patryk Jurczak, Janusz ACS Omega [Image: see text] We present the synthesis of 17 macrocyclic compounds having the structure of so-called unclosed cryptands, acting as anion receptors. These compounds possess amide functions playing the role of hydrogen-bond-donating systems. We have synthesized the presented compounds both by standard methods (using batch conditions) and by static combinatorial chemistry methods, using tetrabutylammonium dihydrogen phosphate as a template, promoting the lariat arm postfunctionalization reaction. American Chemical Society 2020-09-30 /pmc/articles/PMC7558039/ /pubmed/33073154 http://dx.doi.org/10.1021/acsomega.0c04228 Text en This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Niedbała, Patryk
Jurczak, Janusz
One-Pot Parallel Synthesis of Unclosed Cryptands—Searching for Selective Anion Receptors via Static Combinatorial Chemistry Techniques
title One-Pot Parallel Synthesis of Unclosed Cryptands—Searching for Selective Anion Receptors via Static Combinatorial Chemistry Techniques
title_full One-Pot Parallel Synthesis of Unclosed Cryptands—Searching for Selective Anion Receptors via Static Combinatorial Chemistry Techniques
title_fullStr One-Pot Parallel Synthesis of Unclosed Cryptands—Searching for Selective Anion Receptors via Static Combinatorial Chemistry Techniques
title_full_unstemmed One-Pot Parallel Synthesis of Unclosed Cryptands—Searching for Selective Anion Receptors via Static Combinatorial Chemistry Techniques
title_short One-Pot Parallel Synthesis of Unclosed Cryptands—Searching for Selective Anion Receptors via Static Combinatorial Chemistry Techniques
title_sort one-pot parallel synthesis of unclosed cryptands—searching for selective anion receptors via static combinatorial chemistry techniques
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7558039/
https://www.ncbi.nlm.nih.gov/pubmed/33073154
http://dx.doi.org/10.1021/acsomega.0c04228
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