Metal Organic Framework Derived MnO(2)-Carbon Nanotubes for Efficient Oxygen Reduction Reaction and Arsenic Removal from Contaminated Water

Even though manganese oxides are attractive materials for batteries, super-capacitors and electro-catalysts for oxygen reduction reactions, in most practical applications MnO(2) needs to be hybridized with conductive carbon nano-structures to overcome its inherent poor electrical conductivity. In this manuscript we report microwave-assisted synthesis of MnO(2) embedded carbon nanotubes (MnO(2)@CNT) from Mn-H(3)BTC (benzene-1,3,5-carboxylic acid) metal organic frameworks (MOF) precursors. Using graphene oxide as microwave susceptible surface, MnO(2) nano-particles embedded in three dimensional reduced graphene oxide (rGO) -CNT frameworks (MnO(2)@CNT-rGO) were synthesized which when applied as electro-catalysts in oxygen reduction reaction (ORR) demonstrated comparable half-wave potential to commercial Pt/C, better stability, and excellent immunity to methanol crossover effect in alkaline media. When carbon fiber (CF) was used as substrate, three-dimensional MnO(2)@CNT-CF were obtained whose utility as effective adsorbents for arsenic removal from contaminated waters is demonstrated.