Electrospinning Synthesis of Carbon-Supported Pt(3)Mn Intermetallic Nanocrystals and Electrocatalytic Performance towards Oxygen Reduction Reaction

To realize the large-scale application of fuel cells, it is still a great challenge to improve the performance and reduce the cost of cathode catalysts towards oxygen reduction reaction (ORR). In this work, carbon-supported ordered Pt(3)Mn intermetallic catalysts were prepared by thermal annealing electrospun polyacrylonitrile nanofibers containing Platinum(II) acetylacetonate/ Manganese(III) acetylacetonate. Compared with its counterparts, the ordered Pt(3)Mn intermetallic obtained at 950 °C exhibits a more positive half-potential and higher kinetic current density during the ORR process. Benefiting from their defined stoichiometry and crystal structure, the Mn atoms in Pt(3)Mn intermetallic can modulate well the geometric and electronic structure of surface Pt atoms, endowing Pt(3)Mn catalyst with an enhanced ORR catalytic activity. Moreover, it also has a better catalytic stability and methanol tolerance than commercial Pt/C catalyst. Our study provides a new strategy to fabricate a highly active and durable Pt(3)Mn intermetallic electrocatalyst towards ORR.