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Effect of a Monomer Composition on the Mechanical Properties and Glass Transition Temperature of a Waterborne Polyurethane/Graphene Oxide and Waterborne Polyurethane/MWCNT Nanocomposite
Anionic waterborne polyurethane (aWPU) is not compatible with graphene oxide (GO) due to the repulsive force acting on identical ionic charges. In this study, we fabricated cationic surfactant treated GO and cationic surfactant treated carbon nanotube (CNT) to increase the compatibility with aWPU. C...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7563110/ https://www.ncbi.nlm.nih.gov/pubmed/32899305 http://dx.doi.org/10.3390/polym12092013 |
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author | Kim, Hyung Joong Han, Jihye Son, Younggon |
author_facet | Kim, Hyung Joong Han, Jihye Son, Younggon |
author_sort | Kim, Hyung Joong |
collection | PubMed |
description | Anionic waterborne polyurethane (aWPU) is not compatible with graphene oxide (GO) due to the repulsive force acting on identical ionic charges. In this study, we fabricated cationic surfactant treated GO and cationic surfactant treated carbon nanotube (CNT) to increase the compatibility with aWPU. Cationic waterborne polyurethane (WPU) and nanocomposites thereof were also prepared. On the basis of the mechanical properties of the nanocomposites, glass transition temperature (T(g)), and a stability test, it was found that the compatibility between WPU and a nanofiller (NF) was enhanced to a great extent when WPU and NF had opposite ionicity. The T(g) and mechanical properties of WPU increased with the addition of NF, showed the maximum value and thereafter decreased with further addition. The effect of composition of ionic monomer in WPU was also investigated. As the composition of the ionic monomer increases, the concentration of NF for the maximum T(g) and mechanical properties increases. This was attributed to the ionic association between the NF and WPU. |
format | Online Article Text |
id | pubmed-7563110 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-75631102020-10-27 Effect of a Monomer Composition on the Mechanical Properties and Glass Transition Temperature of a Waterborne Polyurethane/Graphene Oxide and Waterborne Polyurethane/MWCNT Nanocomposite Kim, Hyung Joong Han, Jihye Son, Younggon Polymers (Basel) Article Anionic waterborne polyurethane (aWPU) is not compatible with graphene oxide (GO) due to the repulsive force acting on identical ionic charges. In this study, we fabricated cationic surfactant treated GO and cationic surfactant treated carbon nanotube (CNT) to increase the compatibility with aWPU. Cationic waterborne polyurethane (WPU) and nanocomposites thereof were also prepared. On the basis of the mechanical properties of the nanocomposites, glass transition temperature (T(g)), and a stability test, it was found that the compatibility between WPU and a nanofiller (NF) was enhanced to a great extent when WPU and NF had opposite ionicity. The T(g) and mechanical properties of WPU increased with the addition of NF, showed the maximum value and thereafter decreased with further addition. The effect of composition of ionic monomer in WPU was also investigated. As the composition of the ionic monomer increases, the concentration of NF for the maximum T(g) and mechanical properties increases. This was attributed to the ionic association between the NF and WPU. MDPI 2020-09-03 /pmc/articles/PMC7563110/ /pubmed/32899305 http://dx.doi.org/10.3390/polym12092013 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Kim, Hyung Joong Han, Jihye Son, Younggon Effect of a Monomer Composition on the Mechanical Properties and Glass Transition Temperature of a Waterborne Polyurethane/Graphene Oxide and Waterborne Polyurethane/MWCNT Nanocomposite |
title | Effect of a Monomer Composition on the Mechanical Properties and Glass Transition Temperature of a Waterborne Polyurethane/Graphene Oxide and Waterborne Polyurethane/MWCNT Nanocomposite |
title_full | Effect of a Monomer Composition on the Mechanical Properties and Glass Transition Temperature of a Waterborne Polyurethane/Graphene Oxide and Waterborne Polyurethane/MWCNT Nanocomposite |
title_fullStr | Effect of a Monomer Composition on the Mechanical Properties and Glass Transition Temperature of a Waterborne Polyurethane/Graphene Oxide and Waterborne Polyurethane/MWCNT Nanocomposite |
title_full_unstemmed | Effect of a Monomer Composition on the Mechanical Properties and Glass Transition Temperature of a Waterborne Polyurethane/Graphene Oxide and Waterborne Polyurethane/MWCNT Nanocomposite |
title_short | Effect of a Monomer Composition on the Mechanical Properties and Glass Transition Temperature of a Waterborne Polyurethane/Graphene Oxide and Waterborne Polyurethane/MWCNT Nanocomposite |
title_sort | effect of a monomer composition on the mechanical properties and glass transition temperature of a waterborne polyurethane/graphene oxide and waterborne polyurethane/mwcnt nanocomposite |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7563110/ https://www.ncbi.nlm.nih.gov/pubmed/32899305 http://dx.doi.org/10.3390/polym12092013 |
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