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Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−)
Reaction of the trilacunary Wells−Dawson anion {α-P(2)W(15)O(56)}(12−) with Er(III) ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−) (1). The isolated compound was structurally charac...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7570939/ https://www.ncbi.nlm.nih.gov/pubmed/32942657 http://dx.doi.org/10.3390/molecules25184229 |
Sumario: | Reaction of the trilacunary Wells−Dawson anion {α-P(2)W(15)O(56)}(12−) with Er(III) ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−) (1). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of 1 were investigated. |
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