Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−)

Reaction of the trilacunary Wells−Dawson anion {α-P(2)W(15)O(56)}(12−) with Er(III) ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−) (1). The isolated compound was structurally charac...

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Autores principales: Ibrahim, Masooma, Baksi, Ananya, Peng, Yan, Al-Zeidaneen, Firas Khalil, Mbomekallé, Israël M., de Oliveira, Pedro, Anson, Christopher E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7570939/
https://www.ncbi.nlm.nih.gov/pubmed/32942657
http://dx.doi.org/10.3390/molecules25184229
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author Ibrahim, Masooma
Baksi, Ananya
Peng, Yan
Al-Zeidaneen, Firas Khalil
Mbomekallé, Israël M.
de Oliveira, Pedro
Anson, Christopher E.
author_facet Ibrahim, Masooma
Baksi, Ananya
Peng, Yan
Al-Zeidaneen, Firas Khalil
Mbomekallé, Israël M.
de Oliveira, Pedro
Anson, Christopher E.
author_sort Ibrahim, Masooma
collection PubMed
description Reaction of the trilacunary Wells−Dawson anion {α-P(2)W(15)O(56)}(12−) with Er(III) ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−) (1). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of 1 were investigated.
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spelling pubmed-75709392020-10-28 Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−) Ibrahim, Masooma Baksi, Ananya Peng, Yan Al-Zeidaneen, Firas Khalil Mbomekallé, Israël M. de Oliveira, Pedro Anson, Christopher E. Molecules Article Reaction of the trilacunary Wells−Dawson anion {α-P(2)W(15)O(56)}(12−) with Er(III) ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−) (1). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of 1 were investigated. MDPI 2020-09-15 /pmc/articles/PMC7570939/ /pubmed/32942657 http://dx.doi.org/10.3390/molecules25184229 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ibrahim, Masooma
Baksi, Ananya
Peng, Yan
Al-Zeidaneen, Firas Khalil
Mbomekallé, Israël M.
de Oliveira, Pedro
Anson, Christopher E.
Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−)
title Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−)
title_full Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−)
title_fullStr Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−)
title_full_unstemmed Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−)
title_short Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H(2)O)(CH(3)COO)(P(2)W(17)O(61))}(2)](16−)
title_sort synthesis, characterization, electrochemistry, photoluminescence and magnetic properties of a dinuclear erbium(iii)-containing monolacunary dawson-type tungstophosphate: [{er(h(2)o)(ch(3)coo)(p(2)w(17)o(61))}(2)](16−)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7570939/
https://www.ncbi.nlm.nih.gov/pubmed/32942657
http://dx.doi.org/10.3390/molecules25184229
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