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Influence of the Nucleophilic Ligand on the Reactivity of Carbonyl Rhenium(I) Complexes towards Methyl Propiolate: A Computational Chemistry Perspective

A comparative theoretical study on the reactivity of the complexes [ReY(CO)(3)(bipy)] (Y = NH(2), NHMe, NHpTol, OH, OMe, OPh, PH(2), PHMe, PMe(2), PHPh, PPh(2), PMePh, SH, SMe, SPh; bipy = 2,2′-bipyridine) towards methyl propiolate was carried out to analyze the influence of both the heteroatom (N,...

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Detalles Bibliográficos
Autores principales:	Álvarez, Daniel, López-Castro, Elena, Guerrero, Arturo, Riera, Lucía, Pérez, Julio, Díaz, Jesús, Menéndez, M. Isabel, López, Ramón
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7571231/ https://www.ncbi.nlm.nih.gov/pubmed/32927650 http://dx.doi.org/10.3390/molecules25184134

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