Cargando…

Optimization of a Decatungstate-Catalyzed C(sp(3))–H Alkylation Using a Continuous Oscillatory Millistructured Photoreactor

[Image: see text] Tetrabutylammonium decatungstate (TBADT) has emerged as an efficient and versatile photocatalyst for hydrogen atom transfer (HAT) processes that enables the cleavage of both activated and unactivated aliphatic C–H bonds. Using a recently developed oscillatory millistructured contin...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wen, Zhenghui, Maheshwari, Apoorva, Sambiagio, Carlo, Deng, Yuchao, Laudadio, Gabriele, Van Aken, Koen, Sun, Yuhan, Gemoets, Hannes P. L., Noël, Timothy
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7573979/ https://www.ncbi.nlm.nih.gov/pubmed/33100815 http://dx.doi.org/10.1021/acs.oprd.0c00235

Ejemplares similares

Accelerated and Scalable C(sp(3))–H Amination via Decatungstate Photocatalysis Using a Flow Photoreactor Equipped with High-Intensity LEDs
por: Wan, Ting, et al.
Publicado: (2021)

Selective C(sp(3))−H Aerobic Oxidation Enabled by Decatungstate Photocatalysis in Flow
por: Laudadio, Gabriele, et al.
Publicado: (2018)

Decatungstate‐Mediated C(sp(3))–H Heteroarylation via Radical‐Polar Crossover in Batch and Flow
por: Wan, Ting, et al.
Publicado: (2021)

Decatungstate-catalyzed radical disulfuration through direct C-H functionalization for the preparation of unsymmetrical disulfides
por: Zhang, Jingjing, et al.
Publicado: (2022)

Iron‐Catalyzed Cross‐Coupling of Alkynyl and Styrenyl Chlorides with Alkyl Grignard Reagents in Batch and Flow
por: Deng, Yuchao, et al.
Publicado: (2019)

Development and application of decatungstate catalyzed C–H (18)F- and (19)F-fluorination, fluoroalkylation and beyond
por: Yuan, Zheliang, et al.
Publicado: (2023)

Modular allylation of C(sp(3))–H bonds by combining decatungstate photocatalysis and HWE olefination in flow
por: Capaldo, Luca, et al.
Publicado: (2022)

Selective and scalable oxygenation of heteroatoms using the elements of nature: air, water, and light
por: Diprima, Damiano, et al.
Publicado: (2023)

Flow Synthesis of Diaryliodonium Triflates
por: Laudadio, Gabriele, et al.
Publicado: (2017)

Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation
por: Capaldo, Luca, et al.
Publicado: (2021)

Photocatalytic deaminative benzylation and alkylation of tetrahydroisoquinolines with N-alkylpyrydinium salts
por: Schönbauer, David, et al.
Publicado: (2020)

A Modular Flow Design for the meta‐Selective C−H Arylation of Anilines
por: Gemoets, Hannes P. L., et al.
Publicado: (2017)

Inductive Tracking Methodology for Wireless Sensors in Photoreactors
por: Demetz, David, et al.
Publicado: (2021)

Low-Cost Photoreactor to Monitor Wastewater Pollutant Decomposition
por: Ruiz-Flores, Alberto, et al.
Publicado: (2023)

Photochemistry with laser radiation in condensed phase using miniaturized photoreactors
por: Bremus-Köbberling, Elke, et al.
Publicado: (2012)

Development of a modular photoreactor for the upscaling of continuous flow photochemistry
por: Hermens, Johannes G. H., et al.
Publicado: (2022)

Conversion of Racemic Alkyl Aryl Sulfoxides into Pure Enantiomers Using a Recycle Photoreactor: Tandem Use of Chromatography on Chiral Support and Photoracemization on Solid Support
por: Tozawa, Kumi, et al.
Publicado: (2023)

Visible‐Light‐Promoted Iron‐Catalyzed C(sp(2))–C(sp(3)) Kumada Cross‐Coupling in Flow
por: Wei, Xiao‐Jing, et al.
Publicado: (2019)

Electrochemical Nickel-Catalyzed C(sp(3))–C(sp(3)) Cross-Coupling of Alkyl Halides with Alkyl Tosylates
por: Ibrahim, Malek Y. S., et al.
Publicado: (2023)

A kinetic study for the Fenton and photo-Fenton paracetamol degradation in an annular photoreactor
por: Audino, Francesca, et al.
Publicado: (2018)

Role of lamp type in conventional batch and micro-photoreactor for photocatalytic hydrogen production
por: Meinhardová, Vendula, et al.
Publicado: (2023)

Nickel-catalyzed migratory alkyl–alkyl cross-coupling reaction
por: Li, Yangyang, et al.
Publicado: (2020)

Using High-Power UV-LED to Accelerate a Decatungstate-Anion-Catalyzed Reaction: A Model Study for the Quick Oxidation of Benzyl Alcohol to Benzoic Acid Using Molecular Oxygen
por: Hyodo, Mamoru, et al.
Publicado: (2021)

Rhodium-catalyzed direct alkylation of benzylic amines using alkyl bromides
por: Anschuber, Martin, et al.
Publicado: (2018)

Palladium-catalyzed asymmetric allylic alkylation (AAA) with alkyl sulfones as nucleophiles
por: Trost, Barry M., et al.
Publicado: (2021)

Regioselective Pd-catalyzed α-alkylation of furans using alkyl iodides
por: Yuan, Jiaqi, et al.
Publicado: (2021)

Copper-catalyzed direct alkylation of heteroarenes
por: Theunissen, Cédric, et al.
Publicado: (2017)

Chromium‐Catalyzed Alkylation of Amines by Alcohols
por: Kallmeier, Fabian, et al.
Publicado: (2020)

Phase-Transfer-Catalyzed Alkylation of Hydantoins
por: Keenan, Thomas, et al.
Publicado: (2022)

Optimisation of the synthesis of vancomycin-selective molecularly imprinted polymer nanoparticles using automatic photoreactor
por: Muzyka, Kateryna, et al.
Publicado: (2014)

Dawn of a new era in industrial photochemistry: the scale-up of micro- and mesostructured photoreactors
por: Kayahan, Emine, et al.
Publicado: (2020)

Accelerating fragment-based library generation by coupling high-performance photoreactors with benchtop analysis
por: Lefebvre, Quentin, et al.
Publicado: (2020)

Correction to: A kinetic study for the Fenton and photo-Fenton paracetamol degradation in an annular photoreactor
por: Audino, Francesca, et al.
Publicado: (2021)

Investigation of CO(2) Photoreduction in an Annular Fluidized Bed Photoreactor by MP-PIC Simulation
por: Lu, Xuesong, et al.
Publicado: (2022)

Iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation
por: Sarkar, Rahul, et al.
Publicado: (2021)

Waveguide photoreactor enhances solar fuels photon utilization towards maximal optoelectronic – photocatalytic synergy
por: Loh, Joel Y. Y., et al.
Publicado: (2021)

β-Mannanase-catalyzed synthesis of alkyl mannooligosides
por: Morrill, Johan, et al.
Publicado: (2018)

HOTf-Catalyzed Alkyl-Heck-type Reaction
por: Zhou, Huan, et al.
Publicado: (2018)

Rh-catalyzed alkoxycarbonylation of unactivated alkyl chlorides
por: Wang, Peng, et al.
Publicado: (2022)

Fe-catalyzed Decarbonylative Alkylative Spirocyclization of N-Arylcinnamamides: Access to Alkylated 1-Azaspirocyclohexadienones
por: Peng, Xiang, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_pv82arvatu87vup4seunfeerse