Quasiphonon polaritons

Mid-infrared reflection spectra of c- and m-plane bulk AlN show a reststrahlen band related to the formation of phonon polaritons. However, it is worth noting that there are additional hump- and spike-shaped peaks in the spectra, which cannot be explained by the phonon-polaritons model applicable to optically isotropic crystals. Here, considering the existence of quasiphonons in wurtzite crystals, we suppose that the extra peaks result from the generation of quasiphonon polaritons (QPPs) induced by the coupling between photon and quasi-transverse optical phonon. On the basis of this point, a QPPs model applicable to optically anisotropic wurtzite crystals is developed, which successfully explains the reststrahlen band of bulk AlN. Besides, on the ground of our model, a series of reststrahlen band of bulk AlN under various configurations is also predicted and presented.