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Activation of N(2)O and SO(2) by the P–B Bond System. Reversible Binding of SO(2) by the P–O–B Geminal Frustrated Lewis Pair
[Image: see text] Herein, we present the first transformation of borylphosphine into borylphosphinite using nitrous oxide. Borylphosphine reacts with N(2)O via insertion of a single oxygen atom into the P–B bond and formation of a P–O–B bond system. Borylphosphine and borylphosphinite capture SO(2)...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7588030/ https://www.ncbi.nlm.nih.gov/pubmed/32286811 http://dx.doi.org/10.1021/acs.inorgchem.0c00435 |