Activation of N(2)O and SO(2) by the P–B Bond System. Reversible Binding of SO(2) by the P–O–B Geminal Frustrated Lewis Pair

[Image: see text] Herein, we present the first transformation of borylphosphine into borylphosphinite using nitrous oxide. Borylphosphine reacts with N(2)O via insertion of a single oxygen atom into the P–B bond and formation of a P–O–B bond system. Borylphosphine and borylphosphinite capture SO(2)...

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Detalles Bibliográficos
Autores principales: Szynkiewicz, Natalia, Chojnacki, Jarosław, Grubba, Rafał
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7588030/
https://www.ncbi.nlm.nih.gov/pubmed/32286811
http://dx.doi.org/10.1021/acs.inorgchem.0c00435
Descripción
Sumario:[Image: see text] Herein, we present the first transformation of borylphosphine into borylphosphinite using nitrous oxide. Borylphosphine reacts with N(2)O via insertion of a single oxygen atom into the P–B bond and formation of a P–O–B bond system. Borylphosphine and borylphosphinite capture SO(2) and activate it in an irreversible and reversible manner, respectively.

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