Stereoselective Synthesis of Tropanes via a 6π‐Electrocyclic Ring‐Opening/ Huisgen [3+2]‐Cycloaddition Cascade of Monocyclopropanated Heterocycles

The synthesis of tropanes via a microwave‐assisted, stereoselective 6π‐electrocyclic ring‐opening/ Huisgen [3+2]‐cycloaddition cascade of cyclopropanated pyrrole and furan derivatives with electron‐deficient dipolarophiles is demonstrated. Starting from furans or pyrroles, 8‐aza‐ and 8‐oxabicyclo[3....

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Detalles Bibliográficos
Autores principales: Sonnleitner, Carina M., Park, Saerom, Eckl, Robert, Ertl, Thomas, Reiser, Oliver
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589232/
https://www.ncbi.nlm.nih.gov/pubmed/32627302
http://dx.doi.org/10.1002/anie.202006030

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589232/
https://www.ncbi.nlm.nih.gov/pubmed/32627302
http://dx.doi.org/10.1002/anie.202006030

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