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Cs[Cl(3)F(10)]: A Propeller‐Shaped [Cl(3)F(10)](−) Anion in a Peculiar A([5])B([5]) Structure Type
Reaction of CsF with ClF(3) leads to Cs[Cl(3)F(10)]. It contains a molecular, propeller‐shaped [Cl(3)F(10)](−) anion with a central μ(3)‐F atom and three T‐shaped ClF(3) molecules coordinated to it. This anion represents the first example of a heteropolyhalide anion of higher ClF(3) content than [Cl...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589245/ https://www.ncbi.nlm.nih.gov/pubmed/32608053 http://dx.doi.org/10.1002/anie.202007019 |