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Cs[Cl(3)F(10)]: A Propeller‐Shaped [Cl(3)F(10)](−) Anion in a Peculiar A([5])B([5]) Structure Type

Reaction of CsF with ClF(3) leads to Cs[Cl(3)F(10)]. It contains a molecular, propeller‐shaped [Cl(3)F(10)](−) anion with a central μ(3)‐F atom and three T‐shaped ClF(3) molecules coordinated to it. This anion represents the first example of a heteropolyhalide anion of higher ClF(3) content than [Cl...

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Detalles Bibliográficos
Autores principales:	Scheibe, Benjamin, Karttunen, Antti J., Müller, Ulrich, Kraus, Florian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589245/ https://www.ncbi.nlm.nih.gov/pubmed/32608053 http://dx.doi.org/10.1002/anie.202007019

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