Cargando…

Highly Stable, Readily Reducible, Fluorescent, Trifluoromethylated 9‐Borafluorenes

Three different perfluoroalkylated borafluorenes ((F) Bf) were prepared and their electronic and photophysical properties were investigated. The systems have four trifluoromethyl moieties on the borafluorene moiety as well as two trifluoromethyl groups at the ortho positions of their exo‐aryl moieti...

Descripción completa

Detalles Bibliográficos
Autores principales:	Rauch, Florian, Fuchs, Sonja, Friedrich, Alexandra, Sieh, Daniel, Krummenacher, Ivo, Braunschweig, Holger, Finze, Maik, Marder, Todd B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7589458/ https://www.ncbi.nlm.nih.gov/pubmed/31999019 http://dx.doi.org/10.1002/chem.201905559

Ejemplares similares

N‐Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds
por: He, Jiang, et al.
Publicado: (2019)

Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives
por: Krebs, Johannes, et al.
Publicado: (2022)

Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene
por: Bischof, Tobias, et al.
Publicado: (2022)

An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers
por: Rauch, Florian, et al.
Publicado: (2020)

Electronically Driven Regioselective Iridium‐Catalyzed C−H Borylation of Donor‐π‐Acceptor Chromophores Containing Triarylboron Acceptors
por: Rauch, Florian, et al.
Publicado: (2020)

Synthesis and Structure of an o‐Carboranyl‐Substituted Three‐Coordinate Borane Radical Anion
por: Krebs, Johannes, et al.
Publicado: (2021)

Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning
por: Narsaria, Ayush K., et al.
Publicado: (2020)

Phenylpyridyl‐Fused Boroles: A Unique Coordination Mode and Weak B−N Coordination‐Induced Dual Fluorescence
por: He, Jiang, et al.
Publicado: (2021)

Highly Emissive 9‐Borafluorene Derivatives: Synthesis, Photophysical Properties and Device Fabrication
por: Chen, Xing, et al.
Publicado: (2021)

Synthesis, Photophysical and Electronic Properties of New Red‐to‐NIR Emitting Donor–Acceptor Pyrene Derivatives
por: Merz, Julia, et al.
Publicado: (2019)

Persistent Borafluorene Radicals
por: Yang, Wenlong, et al.
Publicado: (2020)

Synthesis, Photophysical and Electronic Properties of Mono‐, Di‐, and Tri‐Amino‐Substituted Ortho‐Perylenes, and Comparison to the Tetra‐Substituted Derivative
por: Merz, Julia, et al.
Publicado: (2020)

9-Bromo-9-borafluorene
por: Hübner, Alexander, et al.
Publicado: (2010)

(Hetero)arene-fused boroles: a broad spectrum of applications
por: He, Jiang, et al.
Publicado: (2020)

Rethinking Borole Cycloaddition Reactivity
por: Lindl, Felix, et al.
Publicado: (2021)

Synthesis of Highly Functionalizable Symmetrically and Unsymmetrically Substituted Triarylboranes from Bench‐Stable Boron Precursors
por: Ferger, Matthias, et al.
Publicado: (2021)

2‐ and 2,7‐Substituted para‐N‐Methylpyridinium Pyrenes: Syntheses, Molecular and Electronic Structures, Photophysical, Electrochemical, and Spectroelectrochemical Properties and Binding to Double‐Stranded (ds) DNA
por: Kole, Goutam Kumar, et al.
Publicado: (2021)

Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF(3)(+), CF(3)(•), and CF(3)(–) Reactivity
por: Jia, Hao, et al.
Publicado: (2021)

Electron‐Rich EDOT Linkers in Tetracationic bis‐Triarylborane Chromophores: Influence on Water Stability, Biomacromolecule Sensing, and Photoinduced Cytotoxicity
por: Ferger, Matthias, et al.
Publicado: (2022)

Phosphinoborylenes as stable sources of fleeting borylenes
por: Pranckevicius, Conor, et al.
Publicado: (2020)

Bis(phenylethynyl)arene Linkers in Tetracationic Bis‐triarylborane Chromophores Control Fluorimetric and Raman Sensing of Various DNAs and RNAs
por: Ferger, Matthias, et al.
Publicado: (2021)

Bithiophene‐Cored, mono‐, bis‐, and tris‐(Trimethylammonium)‐Substituted, bis‐Triarylborane Chromophores: Effect of the Number and Position of Charges on Cell Imaging and DNA/RNA Sensing
por: Berger, Sarina M., et al.
Publicado: (2021)

Base‐Mediated Radical Borylation of Alkyl Sulfones
por: Huang, Mingming, et al.
Publicado: (2021)

Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes
por: Lenczyk, Carsten, et al.
Publicado: (2019)

Improved Synthesis of 2-Trifluoromethyl-10-aminopropylphenothiazine: Making 2-Trifluoromethyl-10-aminopropylphenothiazine Readily Available for Calmodulin Purification
por: Johnson, Josiah W., et al.
Publicado: (2018)

Cu and Hydroquinone for the Trifluoromethylation of Unprotected Phenols
por: Pletz, Jakob, et al.
Publicado: (2018)

Tetracationic Bis‐Triarylborane 1,3‐Butadiyne as a Combined Fluorimetric and Raman Probe for Simultaneous and Selective Sensing of Various DNA, RNA, and Proteins
por: Amini, Hashem, et al.
Publicado: (2020)

Controlled Synthesis of Oligomers Containing Main‐Chain B(sp(2))‐B(sp(2)) Bonds
por: Schorr, Fabian, et al.
Publicado: (2021)

Dithiophene‐Fused Oxadiborepins and Azadiborepins: A New Class of Highly Fluorescent Heteroaromatics
por: Crumbach, Merian, et al.
Publicado: (2021)

cAAC‐Stabilized 9,10‐diboraanthracenes—Acenes with Open‐Shell Singlet Biradical Ground States
por: Saalfrank, Christian, et al.
Publicado: (2020)

Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent
por: Egami, Hiromichi, et al.
Publicado: (2015)

Diboramacrocycles: reversible borole dimerisation–dissociation systems
por: Fuchs, Sonja, et al.
Publicado: (2022)

One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds
por: Jia, Xiangqing, et al.
Publicado: (2021)

The 9H‐9‐Borafluorene Dianion: A Surrogate for Elusive Diarylboryl Anion Nucleophiles
por: Gilmer, Jannik, et al.
Publicado: (2020)

Trifluoromethyl-substituted tetrathiafulvalenes
por: Jeannin, Olivier, et al.
Publicado: (2015)

Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-substituted ortho-perylenes displaying four reversible oxidations or reductions
por: Merz, Julia, et al.
Publicado: (2019)

Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
por: Hagspiel, Stephan, et al.
Publicado: (2019)

Stable and Storable N(CF(3))(2) Transfer Reagents
por: Schneider, Leon N., et al.
Publicado: (2021)

Use of Fluorescent Dyes for Readily Recognizing Sperm Damage
por: Farah, Omar Ibrahim, et al.
Publicado: (2013)

Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene
por: Kuntze-Fechner, Maximilian W., et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_fcbfq8fu8n85as80ffr4v494k1