Cargando…

An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers

Using a new divergent approach, conjugated triarylborane dendrimers were synthesized up to the 2(nd) generation. The synthetic strategy consists of three steps: 1) functionalization, via iridium catalyzed C−H borylation; 2) activation, via fluorination of the generated boronate ester with K[HF(2)] o...

Descripción completa

Detalles Bibliográficos
Autores principales:	Rauch, Florian, Endres, Peter, Friedrich, Alexandra, Sieh, Daniel, Hähnel, Martin, Krummenacher, Ivo, Braunschweig, Holger, Finze, Maik, Ji, Lei, Marder, Todd B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7590090/ https://www.ncbi.nlm.nih.gov/pubmed/32428359 http://dx.doi.org/10.1002/chem.202001985

Ejemplares similares

Synthesis and Structure of an o‐Carboranyl‐Substituted Three‐Coordinate Borane Radical Anion
por: Krebs, Johannes, et al.
Publicado: (2021)

Highly Stable, Readily Reducible, Fluorescent, Trifluoromethylated 9‐Borafluorenes
por: Rauch, Florian, et al.
Publicado: (2020)

N‐Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds
por: He, Jiang, et al.
Publicado: (2019)

Electronically Driven Regioselective Iridium‐Catalyzed C−H Borylation of Donor‐π‐Acceptor Chromophores Containing Triarylboron Acceptors
por: Rauch, Florian, et al.
Publicado: (2020)

Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning
por: Narsaria, Ayush K., et al.
Publicado: (2020)

Phenylpyridyl‐Fused Boroles: A Unique Coordination Mode and Weak B−N Coordination‐Induced Dual Fluorescence
por: He, Jiang, et al.
Publicado: (2021)

Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives
por: Krebs, Johannes, et al.
Publicado: (2022)

Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene
por: Bischof, Tobias, et al.
Publicado: (2022)

Synthesis, Photophysical and Electronic Properties of New Red‐to‐NIR Emitting Donor–Acceptor Pyrene Derivatives
por: Merz, Julia, et al.
Publicado: (2019)

(Hetero)arene-fused boroles: a broad spectrum of applications
por: He, Jiang, et al.
Publicado: (2020)

Base‐Mediated Radical Borylation of Alkyl Sulfones
por: Huang, Mingming, et al.
Publicado: (2021)

2005 Lijiang International Starburst Workshop: Extreme Starbursts - Near And Far
Publicado: (2005)

Electron‐Rich EDOT Linkers in Tetracationic bis‐Triarylborane Chromophores: Influence on Water Stability, Biomacromolecule Sensing, and Photoinduced Cytotoxicity
por: Ferger, Matthias, et al.
Publicado: (2022)

Experience with the CES STARBURST
por: Waters, G, et al.
Publicado: (1986)

Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials
por: Bachmann, Jonas, et al.
Publicado: (2022)

9-Ethynyl-1,2-dimethyl-1,2-dicarba-closo-dodecaborane (1,2-Me(2)-9-HC C-closo-1,2-C(2)B(10)H(9))
por: Finze, Maik, et al.
Publicado: (2010)

cAAC‐Stabilized 9,10‐diboraanthracenes—Acenes with Open‐Shell Singlet Biradical Ground States
por: Saalfrank, Christian, et al.
Publicado: (2020)

Synthesis, Photophysical and Electronic Properties of Mono‐, Di‐, and Tri‐Amino‐Substituted Ortho‐Perylenes, and Comparison to the Tetra‐Substituted Derivative
por: Merz, Julia, et al.
Publicado: (2020)

Conference on Starbursts : Triggers, nature and evolution
por: Guiderdoni, Bruno, et al.
Publicado: (1998)

Workshop on Starburst Galaxies: Near and Far
por: Collective
Publicado: (2000)

Workshop in the Neutral ISM in Starburst Galaxies
Publicado: (2003)

Starburst nuclei: ISO observations and models
por: Siebenmorgen, R, et al.
Publicado: (1999)

One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds
por: Jia, Xiangqing, et al.
Publicado: (2021)

Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-substituted ortho-perylenes displaying four reversible oxidations or reductions
por: Merz, Julia, et al.
Publicado: (2019)

Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation
por: Bohlen, Josina L., et al.
Publicado: (2023)

From luminous hot stars to starburst galaxies
por: Conti, Peter S, et al.
Publicado: (2008)

1996 INAOE Conference on Starburst Activity in Galaxies
por: Franco, J, et al.
Publicado: (1996)

Blue nevus with a starburst pattern on dermoscopy
por: Shiga, Takeo, et al.
Publicado: (2012)

Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene
por: Kuntze-Fechner, Maximilian W., et al.
Publicado: (2020)

NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions
por: Kuehn, Laura, et al.
Publicado: (2022)

Rhodium‐Mediated Stoichiometric Synthesis of Mono‐, Bi‐, and Bis‐1,2‐Azaborinines: 1‐Rhoda‐3,2‐azaboroles as Reactive Precursors
por: Heß, Merlin, et al.
Publicado: (2021)

Diphosphino‐Functionalized 1,8‐Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes
por: Cui, Jingjing, et al.
Publicado: (2021)

Aggregation‐Induced Dual Phosphorescence from (o‐Bromophenyl)‐Bis(2,6‐Dimethylphenyl)Borane at Room Temperature
por: Wu, Zhu, et al.
Publicado: (2022)

Starbursts: From 30 Doradus to Lyman Break Galaxies
por: Grijs, Richard, et al.
Publicado: (2005)

Starburst galaxies as important high-energy neutrino factories
por: Ambrosone, Antonio
Publicado: (2021)

Pigmented Bowen’s disease presenting with a “starburst” pattern
por: Maione, Vincenzo, et al.
Publicado: (2016)

Computational Imaging Prediction of Starburst-Effect Diffraction Spikes
por: Lendermann, Markus, et al.
Publicado: (2018)

Rethinking Borole Cycloaddition Reactivity
por: Lindl, Felix, et al.
Publicado: (2021)

2‐ and 2,7‐Substituted para‐N‐Methylpyridinium Pyrenes: Syntheses, Molecular and Electronic Structures, Photophysical, Electrochemical, and Spectroelectrochemical Properties and Binding to Double‐Stranded (ds) DNA
por: Kole, Goutam Kumar, et al.
Publicado: (2021)

Boron: Its Role in Energy‐Related Processes and Applications
por: Huang, Zhenguo, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_i8gcpojpsi2kaiuolugekafdia