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Unusual Nitrene Oxidation Product Formation by Metathesis Involving the Dioxygen O−O and Borylnitrene B−N Bonds
The reaction of dioxygen with nitrenes can have significant energy barriers, although both reactants are triplet diradicals and the formation of nitroso‐O‐oxides is spin‐allowed. By means of matrix‐isolation infrared spectroscopy in solid argon, nitrogen, and neon, and through high‐level computation...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7590100/ https://www.ncbi.nlm.nih.gov/pubmed/32902001 http://dx.doi.org/10.1002/chem.202002445 |