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A Mono‐Substituted Silicon(II) Cation: A Crystalline “Supersilylene”
Mono‐coordinated silicon(II) cations are predicted to be reactive ambiphiles, combining the typically high Lewis acidity of silicon cations with nucleophilicity due to the presence of an electron pair at the same atomic centre. Here, a carbazole‐derived scaffold was used to isolate salts with a mono...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7590127/ https://www.ncbi.nlm.nih.gov/pubmed/32779821 http://dx.doi.org/10.1002/anie.202009874 |