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How Many Pnicogen Bonds can be Formed to a Central Atom Simultaneously?
[Image: see text] A central ZF(3) molecule (Z = P, As, Sb, Bi) is allowed to interact with a number of nucleophiles exemplified by NCH, NH(3), and NC(–) anion. The Z···N pnicogen bond (ZB) to a single base grows stronger for heavier Z atom: P < A < Sb < Bi and follows the NCH < NH(3) <...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7590972/ https://www.ncbi.nlm.nih.gov/pubmed/32052970 http://dx.doi.org/10.1021/acs.jpca.0c00257 |