One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives

One Zn-Nd complex [Zn(2)Nd(4)L(2)(OAc)(10)(OH)(2)(CH(3)OH)(2)] (1) was synthesized from Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H(2)L). 1 shows nanoscale rectangular structure with sizes of about 0.8 × 1.1 × 2.8 nm. 1 exhibits typical near-infrared luminescence of...

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Autores principales: Liu, Xia, Yang, Xiaoping, Ma, Yanan, Liu, Jieni, Shi, Dongliang, Niu, Mengyu, Schipper, Desmond
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7591804/
https://www.ncbi.nlm.nih.gov/pubmed/33195043
http://dx.doi.org/10.3389/fchem.2020.536907
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author Liu, Xia
Yang, Xiaoping
Ma, Yanan
Liu, Jieni
Shi, Dongliang
Niu, Mengyu
Schipper, Desmond
author_facet Liu, Xia
Yang, Xiaoping
Ma, Yanan
Liu, Jieni
Shi, Dongliang
Niu, Mengyu
Schipper, Desmond
author_sort Liu, Xia
collection PubMed
description One Zn-Nd complex [Zn(2)Nd(4)L(2)(OAc)(10)(OH)(2)(CH(3)OH)(2)] (1) was synthesized from Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H(2)L). 1 shows nanoscale rectangular structure with sizes of about 0.8 × 1.1 × 2.8 nm. 1 exhibits typical near-infrared luminescence of Nd(III) under the excitation of UV-visible light. Further study shows that the complex displays luminescent response behavior to anions and nitro explosives, especially with high sensitivity to H(2) [Formula: see text] and 2,4,6-trinitrophenol.
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spelling pubmed-75918042020-11-13 One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives Liu, Xia Yang, Xiaoping Ma, Yanan Liu, Jieni Shi, Dongliang Niu, Mengyu Schipper, Desmond Front Chem Chemistry One Zn-Nd complex [Zn(2)Nd(4)L(2)(OAc)(10)(OH)(2)(CH(3)OH)(2)] (1) was synthesized from Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H(2)L). 1 shows nanoscale rectangular structure with sizes of about 0.8 × 1.1 × 2.8 nm. 1 exhibits typical near-infrared luminescence of Nd(III) under the excitation of UV-visible light. Further study shows that the complex displays luminescent response behavior to anions and nitro explosives, especially with high sensitivity to H(2) [Formula: see text] and 2,4,6-trinitrophenol. Frontiers Media S.A. 2020-10-14 /pmc/articles/PMC7591804/ /pubmed/33195043 http://dx.doi.org/10.3389/fchem.2020.536907 Text en Copyright © 2020 Liu, Yang, Ma, Liu, Shi, Niu and Schipper. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Liu, Xia
Yang, Xiaoping
Ma, Yanan
Liu, Jieni
Shi, Dongliang
Niu, Mengyu
Schipper, Desmond
One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_full One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_fullStr One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_full_unstemmed One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_short One Nanoscale Zn(II)-Nd(III) Complex With Schiff Base Ligand: NIR Luminescent Sensing of Anions and Nitro Explosives
title_sort one nanoscale zn(ii)-nd(iii) complex with schiff base ligand: nir luminescent sensing of anions and nitro explosives
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7591804/
https://www.ncbi.nlm.nih.gov/pubmed/33195043
http://dx.doi.org/10.3389/fchem.2020.536907
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