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Geometric Optimisation of Quantum Thermodynamic Processes
Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7597153/ https://www.ncbi.nlm.nih.gov/pubmed/33286845 http://dx.doi.org/10.3390/e22101076 |
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author | Abiuso, Paolo Miller, Harry J. D. Perarnau-Llobet, Martí Scandi, Matteo |
author_facet | Abiuso, Paolo Miller, Harry J. D. Perarnau-Llobet, Martí Scandi, Matteo |
author_sort | Abiuso, Paolo |
collection | PubMed |
description | Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines. |
format | Online Article Text |
id | pubmed-7597153 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-75971532020-11-09 Geometric Optimisation of Quantum Thermodynamic Processes Abiuso, Paolo Miller, Harry J. D. Perarnau-Llobet, Martí Scandi, Matteo Entropy (Basel) Article Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines. MDPI 2020-09-24 /pmc/articles/PMC7597153/ /pubmed/33286845 http://dx.doi.org/10.3390/e22101076 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Abiuso, Paolo Miller, Harry J. D. Perarnau-Llobet, Martí Scandi, Matteo Geometric Optimisation of Quantum Thermodynamic Processes |
title | Geometric Optimisation of Quantum Thermodynamic Processes |
title_full | Geometric Optimisation of Quantum Thermodynamic Processes |
title_fullStr | Geometric Optimisation of Quantum Thermodynamic Processes |
title_full_unstemmed | Geometric Optimisation of Quantum Thermodynamic Processes |
title_short | Geometric Optimisation of Quantum Thermodynamic Processes |
title_sort | geometric optimisation of quantum thermodynamic processes |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7597153/ https://www.ncbi.nlm.nih.gov/pubmed/33286845 http://dx.doi.org/10.3390/e22101076 |
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