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Geometric Optimisation of Quantum Thermodynamic Processes

Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the...

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Autores principales: Abiuso, Paolo, Miller, Harry J. D., Perarnau-Llobet, Martí, Scandi, Matteo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7597153/
https://www.ncbi.nlm.nih.gov/pubmed/33286845
http://dx.doi.org/10.3390/e22101076
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author Abiuso, Paolo
Miller, Harry J. D.
Perarnau-Llobet, Martí
Scandi, Matteo
author_facet Abiuso, Paolo
Miller, Harry J. D.
Perarnau-Llobet, Martí
Scandi, Matteo
author_sort Abiuso, Paolo
collection PubMed
description Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines.
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spelling pubmed-75971532020-11-09 Geometric Optimisation of Quantum Thermodynamic Processes Abiuso, Paolo Miller, Harry J. D. Perarnau-Llobet, Martí Scandi, Matteo Entropy (Basel) Article Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines. MDPI 2020-09-24 /pmc/articles/PMC7597153/ /pubmed/33286845 http://dx.doi.org/10.3390/e22101076 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Abiuso, Paolo
Miller, Harry J. D.
Perarnau-Llobet, Martí
Scandi, Matteo
Geometric Optimisation of Quantum Thermodynamic Processes
title Geometric Optimisation of Quantum Thermodynamic Processes
title_full Geometric Optimisation of Quantum Thermodynamic Processes
title_fullStr Geometric Optimisation of Quantum Thermodynamic Processes
title_full_unstemmed Geometric Optimisation of Quantum Thermodynamic Processes
title_short Geometric Optimisation of Quantum Thermodynamic Processes
title_sort geometric optimisation of quantum thermodynamic processes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7597153/
https://www.ncbi.nlm.nih.gov/pubmed/33286845
http://dx.doi.org/10.3390/e22101076
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