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Platinum-Catalyzed Hydrosilylation in Polymer Chemistry

This paper addresses a review of platinum-based hydrosilylation catalysts. The main field of application of these catalysts is the curing of silicone polymers. Since the 1960s, this area has developed rapidly in connection with the emergence of new polymer compositions and new areas of application....

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Detalles Bibliográficos
Autores principales: Lukin, Ruslan Yu., Kuchkaev, Aidar M., Sukhov, Aleksandr V., Bekmukhamedov, Giyjaz E., Yakhvarov, Dmitry G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7598247/
https://www.ncbi.nlm.nih.gov/pubmed/32977659
http://dx.doi.org/10.3390/polym12102174
Descripción
Sumario:This paper addresses a review of platinum-based hydrosilylation catalysts. The main field of application of these catalysts is the curing of silicone polymers. Since the 1960s, this area has developed rapidly in connection with the emergence of new polymer compositions and new areas of application. Here we describe general mechanisms of the catalyst activity and the structural effects of the ligands on activity and stability of the catalysts together with the methods for their synthesis.