Cargando…

Regioselective Markovnikov hydrodifluoroalkylation of alkenes using difluoroenoxysilanes

Alkene hydrodifluoroalkylation is a fruitful strategy for synthesizing difluoromethylated compounds that are interesting for developing new medicinal agents, agrochemicals, and advanced materials. Whereas the anti-Markovnikov hydrodifluoroalkylation to linear-type products is developed, employing ra...

Descripción completa

Detalles Bibliográficos
Autores principales:	Hu, Xiao-Si, He, Jun-Xiong, Dong, Su-Zhen, Zhao, Qiu-Hua, Yu, Jin-Sheng, Zhou, Jian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7599245/ https://www.ncbi.nlm.nih.gov/pubmed/33127898 http://dx.doi.org/10.1038/s41467-020-19387-4

Ejemplares similares

Catalytic Hydrodifluoroalkylation of Unactivated Olefins
por: Yue, Wen-Jun, et al.
Publicado: (2022)

Nickel-catalyzed anti-Markovnikov hydroarylation of alkenes
por: Nguyen, Julia, et al.
Publicado: (2019)

Directed Markovnikov hydroarylation and hydroalkenylation of alkenes under nickel catalysis
por: Li, Zi-Qi, et al.
Publicado: (2021)

Mechanistic Insight into the Photoredox Catalysis of Anti-Markovnikov Alkene Hydrofunctionalization Reactions
por: Romero, Nathan A., et al.
Publicado: (2014)

Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes
por: Smith, James R., et al.
Publicado: (2017)

Anti-Markovnikov Intermolecular Hydroamination of Alkenes and Alkynes: A Mechanistic View
por: Escorihuela, Jorge, et al.
Publicado: (2023)

Cobalt-catalyzed regioselective stereoconvergent Markovnikov 1,2-hydrosilylation of conjugated dienes
por: Sang, Hui Leng, et al.
Publicado: (2017)

Catalytic protodeboronation of pinacol boronic esters: formal anti-Markovnikov hydromethylation of alkenes
por: Clausen, Florian, et al.
Publicado: (2019)

Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes
por: Zhu, Shaolin, et al.
Publicado: (2014)

Computational design of high-performance ligand for enantioselective Markovnikov hydroboration of aliphatic terminal alkenes
por: Iwamoto, Hiroaki, et al.
Publicado: (2018)

Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron‐Deficient Platinum Single Atoms
por: Liu, Kairui, et al.
Publicado: (2021)

The formyloxyl radical: electrophilicity, C–H bond activation and anti-Markovnikov selectivity in the oxidation of aliphatic alkenes
por: Somekh, Miriam, et al.
Publicado: (2020)

Markovnikov-Type Hydrotrifluoromethylchalcogenation of Unactivated Terminal Alkenes with [Me(4)N][XCF(3)] (X = S, Se) and TfOH
por: Shi, Jin, et al.
Publicado: (2020)

Regioselective hydroesterification of alkenes and alkenylphenols utilizing CO(2) and hydrosilane
por: Wang, Meng-Meng, et al.
Publicado: (2023)

Photocatalytic nucleophilic addition of alcohols to styrenes in Markovnikov and anti-Markovnikov orientation
por: Weiser, Martin, et al.
Publicado: (2015)

Ligand-modulated nickel-catalyzed regioselective silylalkylation of alkenes
por: Ding, Chao, et al.
Publicado: (2023)

Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes
por: Wickham, Laura M., et al.
Publicado: (2022)

Photoinitiated Multicomponent Anti-Markovnikov Alkoxylation over Graphene Oxide
por: Nie, Liang, et al.
Publicado: (2022)

Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
por: Hu, Meng-Yang, et al.
Publicado: (2018)

Divergent regioselective Heck-type reaction of unactivated alkenes and N-fluoro-sulfonamides
por: Zhao, Chunyang, et al.
Publicado: (2022)

Iron(II) and Copper(I) Control the Total Regioselectivity in the Hydrobromination of Alkenes
por: Cruz, Daniel A., et al.
Publicado: (2021)

Cobalt bis(acetylacetonate)–tert-butyl hydroperoxide–triethylsilane: a general reagent combination for the Markovnikov-selective hydrofunctionalization of alkenes by hydrogen atom transfer
por: Ma, Xiaoshen, et al.
Publicado: (2018)

NiH-catalysed proximal-selective hydroalkylation of unactivated alkenes and the ligand effects on regioselectivity
por: Wang, Xiao-Xu, et al.
Publicado: (2022)

The Nitrilimine–Alkene Cycloaddition Regioselectivity Rationalized by Density Functional Theory Reactivity Indices
por: Molteni, Giorgio, et al.
Publicado: (2017)

Pauson-Khand Reaction of Internal Dissymmetric Trifluoromethyl Alkynes. Influence of the Alkene on the Regioselectivity
por: Aiguabella, Nuria, et al.
Publicado: (2014)

Microwave Assisted Regioselective Bromomethoxylation of Alkenes Using Polymer Supported Bromine Resins
por: Gopalakrishnan, Geetha, et al.
Publicado: (2002)

NiH-catalyzed anti-Markovnikov hydroamidation of unactivated alkenes with 1,4,2-dioxazol-5-ones for the direct synthesis of N-alkyl amides
por: Du, Bingnan, et al.
Publicado: (2022)

Pd-catalyzed anti-Markovnikov selective oxidative amination
por: Kohler, Daniel G., et al.
Publicado: (2018)

Nickel-catalyzed regio- and enantio-selective Markovnikov hydromonofluoroalkylation of 1,3-dienes
por: Liao, Ling, et al.
Publicado: (2022)

Homoleptic octahedral Co(II) complexes as precatalysts for regioselective hydroboration of alkenes with high turnover frequencies
por: Zhang, Guoqi, et al.
Publicado: (2023)

Controllable access to trifluoromethyl-containing indoles and indolines: palladium-catalyzed regioselective functionalization of unactivated alkenes with trifluoroacetimidoyl chlorides
por: Yang, Hefei, et al.
Publicado: (2022)

Rhodium‐Catalyzed Anti‐Markovnikov Transfer Hydroiodination of Terminal Alkynes
por: Boehm, Philip, et al.
Publicado: (2022)

Iron-Mediated Photochemical Anti-Markovnikov Hydroazidation of Unactivated Olefins
por: Lindner, Henry, et al.
Publicado: (2023)

Markovnikov-addition of H-phosphonates to terminal alkynes under metal- and solvent-free conditions
por: Xin, Nana, et al.
Publicado: (2021)

Mechanism, reactivity, and regioselectivity in rhodium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes: a DFT Investigation
por: Qi, Zheng-Hang, et al.
Publicado: (2017)

Hypervalent iodine compounds for anti-Markovnikov-type iodo-oxyimidation of vinylarenes
por: Krylov, Igor B, et al.
Publicado: (2018)

Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles
por: Gribble, Michael W., et al.
Publicado: (2017)

Formic Acid-Driven Rapid and Green Anti-Markovnikov Hydrothiolation of Styrenes
por: Upadhyay, Rahul, et al.
Publicado: (2019)

Anti-Markovnikov hydro(amino)alkylation of vinylarenes via photoredox catalysis
por: Wu, Zhao, et al.
Publicado: (2021)

Boron tribromide as a reagent for anti-Markovnikov addition of HBr to cyclopropanes
por: Gieuw, Matthew H., et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_kvull2tf8v0ttf0kuejk4csl2d