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Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene
Deformation instabilities, such as microbuckling or lamellar fragmentation due to slip localization, play a very important role in the deformation of semicrystalline polymers, although it still not well explored. Such instabilities often appear necessary to modify the deformation path and facilitate...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7599652/ https://www.ncbi.nlm.nih.gov/pubmed/32993078 http://dx.doi.org/10.3390/polym12102208 |
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author | Bartczak, Zbigniew Vozniak, Alina |
author_facet | Bartczak, Zbigniew Vozniak, Alina |
author_sort | Bartczak, Zbigniew |
collection | PubMed |
description | Deformation instabilities, such as microbuckling or lamellar fragmentation due to slip localization, play a very important role in the deformation of semicrystalline polymers, although it still not well explored. Such instabilities often appear necessary to modify the deformation path and facilitate strain accommodation in an energy-minimizing manner. In this work, microbuckling instability was investigated using partially oriented, injection-molded (IM) samples of high-density polyethylene, deformed by a plane-strain compression. Deformed samples were probed by SEM, X-ray (small- and wide-angle X-ray scattering: SAXS, WAXS), and differential scanning calorimetry (DSC). It was found that microbuckling instability, followed quickly by the formation of lamellar kinks, occurred in high-density polyethylene (HDPE) at a true strain of about e = 0.3–0.4, mainly in those lamellar stacks which were initially oriented parallel to the compression direction. This phenomenon was observed with scanning electron microscopy, especially in the oriented skin layers of IM specimens, where a chevron morphology resulting from lamellae microbuckling/kinking was evidenced. Macroscopically, this instability manifested as the so-called “second macroscopic yield” in the form of a hump in the true stress–true strain curve. Microbuckling instability can have a profound effect on the subsequent stages of the deformation process, as well as the resulting structure. This is particularly important in deforming well-oriented lamellar structures—e.g., in drawing pre-oriented films of a semicrystalline polymer, a process commonly used in many technologies. |
format | Online Article Text |
id | pubmed-7599652 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-75996522020-11-01 Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene Bartczak, Zbigniew Vozniak, Alina Polymers (Basel) Article Deformation instabilities, such as microbuckling or lamellar fragmentation due to slip localization, play a very important role in the deformation of semicrystalline polymers, although it still not well explored. Such instabilities often appear necessary to modify the deformation path and facilitate strain accommodation in an energy-minimizing manner. In this work, microbuckling instability was investigated using partially oriented, injection-molded (IM) samples of high-density polyethylene, deformed by a plane-strain compression. Deformed samples were probed by SEM, X-ray (small- and wide-angle X-ray scattering: SAXS, WAXS), and differential scanning calorimetry (DSC). It was found that microbuckling instability, followed quickly by the formation of lamellar kinks, occurred in high-density polyethylene (HDPE) at a true strain of about e = 0.3–0.4, mainly in those lamellar stacks which were initially oriented parallel to the compression direction. This phenomenon was observed with scanning electron microscopy, especially in the oriented skin layers of IM specimens, where a chevron morphology resulting from lamellae microbuckling/kinking was evidenced. Macroscopically, this instability manifested as the so-called “second macroscopic yield” in the form of a hump in the true stress–true strain curve. Microbuckling instability can have a profound effect on the subsequent stages of the deformation process, as well as the resulting structure. This is particularly important in deforming well-oriented lamellar structures—e.g., in drawing pre-oriented films of a semicrystalline polymer, a process commonly used in many technologies. MDPI 2020-09-26 /pmc/articles/PMC7599652/ /pubmed/32993078 http://dx.doi.org/10.3390/polym12102208 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Bartczak, Zbigniew Vozniak, Alina Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene |
title | Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene |
title_full | Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene |
title_fullStr | Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene |
title_full_unstemmed | Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene |
title_short | Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene |
title_sort | microbuckling instability and the second yield during the deformation of semicrystalline polyethylene |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7599652/ https://www.ncbi.nlm.nih.gov/pubmed/32993078 http://dx.doi.org/10.3390/polym12102208 |
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