Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki–Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface

We have established a novel analytical method for solvent polarity on resin surface by combining the synthesis of fluorescent solvatochromic resin with optical waveguide spectrometry. The fluorescent solvatochromic resin was obtained via Suzuki–Miyaura cross-coupling between 4-iodobenzoic acid immob...

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Autores principales: Otsuka, Yu, Li, Guanglei, Takahashi, Hiromi, Satoh, Hisashi, Yamada, Koji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7599713/
https://www.ncbi.nlm.nih.gov/pubmed/33050417
http://dx.doi.org/10.3390/ma13204483
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author Otsuka, Yu
Li, Guanglei
Takahashi, Hiromi
Satoh, Hisashi
Yamada, Koji
author_facet Otsuka, Yu
Li, Guanglei
Takahashi, Hiromi
Satoh, Hisashi
Yamada, Koji
author_sort Otsuka, Yu
collection PubMed
description We have established a novel analytical method for solvent polarity on resin surface by combining the synthesis of fluorescent solvatochromic resin with optical waveguide spectrometry. The fluorescent solvatochromic resin was obtained via Suzuki–Miyaura cross-coupling between 4-iodobenzoic acid immobilized on Wang resin and 5-[4-(N,N-dihexylamino)phenyl]-2-thienylboronic acid N-methyl-iminodiacetic acid (MIDA) ester. The optical waveguide spectrometry studies on the resin showed a strong fluorescent solvatochromism in various organic solvents.
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spelling pubmed-75997132020-11-01 Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki–Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface Otsuka, Yu Li, Guanglei Takahashi, Hiromi Satoh, Hisashi Yamada, Koji Materials (Basel) Article We have established a novel analytical method for solvent polarity on resin surface by combining the synthesis of fluorescent solvatochromic resin with optical waveguide spectrometry. The fluorescent solvatochromic resin was obtained via Suzuki–Miyaura cross-coupling between 4-iodobenzoic acid immobilized on Wang resin and 5-[4-(N,N-dihexylamino)phenyl]-2-thienylboronic acid N-methyl-iminodiacetic acid (MIDA) ester. The optical waveguide spectrometry studies on the resin showed a strong fluorescent solvatochromism in various organic solvents. MDPI 2020-10-10 /pmc/articles/PMC7599713/ /pubmed/33050417 http://dx.doi.org/10.3390/ma13204483 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Otsuka, Yu
Li, Guanglei
Takahashi, Hiromi
Satoh, Hisashi
Yamada, Koji
Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki–Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface
title Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki–Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface
title_full Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki–Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface
title_fullStr Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki–Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface
title_full_unstemmed Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki–Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface
title_short Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki–Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface
title_sort synthesis of a fluorescent solvatochromic resin using suzuki–miyaura cross-coupling and its optical waveguide spectra to measure the solvent polarity on the surface
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7599713/
https://www.ncbi.nlm.nih.gov/pubmed/33050417
http://dx.doi.org/10.3390/ma13204483
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