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Comparative Experimental and Theoretical Study of Mg, Al and Zn Aryloxy Complexes in Copolymerization of Cyclic Esters: The Role of the Metal Coordination in Formation of Random Copolymers

Homogeneity of copolymers is a general problem of catalytic coordination polymerization. In ring-opening polymerization of cyclic esters, the rational design of the catalyst is generally applied to solve this problem by the equalization of the reactivities of comonomers—however, it often leads to a...

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Detalles Bibliográficos
Autores principales: Nifant’ev, Ilya, Komarov, Pavel, Ovchinnikova, Valeriya, Kiselev, Artem, Minyaev, Mikhail, Ivchenko, Pavel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7600584/
https://www.ncbi.nlm.nih.gov/pubmed/33023256
http://dx.doi.org/10.3390/polym12102273