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Enhancing Functionality of Epoxy–TiO(2)-Embedded High-Strength Lightweight Aggregates

With the increasing trend of high-rise, large-scale, and functional modern architectural structures, lightweight aggregate (LWA) concrete that exhibits excellent strength and high functionality has garnered active research attention. In particular, as the properties of concrete vary considerably wit...

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Autores principales: Lim, Taekyung, Lee, Jeong Hui, Mun, Ju-Hyun, Yang, Keun-Hyeok, Ju, Sanghyun, Jeong, Sang-Mi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7602755/
https://www.ncbi.nlm.nih.gov/pubmed/33081225
http://dx.doi.org/10.3390/polym12102384
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author Lim, Taekyung
Lee, Jeong Hui
Mun, Ju-Hyun
Yang, Keun-Hyeok
Ju, Sanghyun
Jeong, Sang-Mi
author_facet Lim, Taekyung
Lee, Jeong Hui
Mun, Ju-Hyun
Yang, Keun-Hyeok
Ju, Sanghyun
Jeong, Sang-Mi
author_sort Lim, Taekyung
collection PubMed
description With the increasing trend of high-rise, large-scale, and functional modern architectural structures, lightweight aggregate (LWA) concrete that exhibits excellent strength and high functionality has garnered active research attention. In particular, as the properties of concrete vary considerably with the raw materials and the proportions of aggregates in the mix, in-depth research on weight reduction, strength improvement, and functional enhancements of aggregates is crucial. This study used the negative pressure coating of a mixed solution comprising epoxy (mixture of epoxy resin and crosslinker), hyper-crosslinked polymer, and titanium oxide (TiO(2)) nanoparticles on the LWA, and achieved an improvement in the strength of the LWA as well as a reduction in air pollutants such as NO(x) and SO(x). Compared to a normal LWA with an aggregate impact value (AIV) of 38.7%, the AIV of the proposed epoxy–TiO(2)-embedded high-strength functional LWA was reduced by approximately half to 21.1%. In addition, the reduction rates of NO(x) and SO(x) gases resulting from the photocatalytic properties of TiO(2) nanoparticles coated with epoxy were approximately 90.9% and 92.8%, respectively. Epoxy–TiO(2), embedded in LWAs through a mixture, exhibited stability, high strength, and a reduction in air pollutant characteristics, despite repeated water washing. The LWA proposed herein offers excellent structural and functional properties and is expected to be used in functional lightweight concrete that can be practically applied in high-rise and large-scale architectural structures.
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spelling pubmed-76027552020-11-01 Enhancing Functionality of Epoxy–TiO(2)-Embedded High-Strength Lightweight Aggregates Lim, Taekyung Lee, Jeong Hui Mun, Ju-Hyun Yang, Keun-Hyeok Ju, Sanghyun Jeong, Sang-Mi Polymers (Basel) Article With the increasing trend of high-rise, large-scale, and functional modern architectural structures, lightweight aggregate (LWA) concrete that exhibits excellent strength and high functionality has garnered active research attention. In particular, as the properties of concrete vary considerably with the raw materials and the proportions of aggregates in the mix, in-depth research on weight reduction, strength improvement, and functional enhancements of aggregates is crucial. This study used the negative pressure coating of a mixed solution comprising epoxy (mixture of epoxy resin and crosslinker), hyper-crosslinked polymer, and titanium oxide (TiO(2)) nanoparticles on the LWA, and achieved an improvement in the strength of the LWA as well as a reduction in air pollutants such as NO(x) and SO(x). Compared to a normal LWA with an aggregate impact value (AIV) of 38.7%, the AIV of the proposed epoxy–TiO(2)-embedded high-strength functional LWA was reduced by approximately half to 21.1%. In addition, the reduction rates of NO(x) and SO(x) gases resulting from the photocatalytic properties of TiO(2) nanoparticles coated with epoxy were approximately 90.9% and 92.8%, respectively. Epoxy–TiO(2), embedded in LWAs through a mixture, exhibited stability, high strength, and a reduction in air pollutant characteristics, despite repeated water washing. The LWA proposed herein offers excellent structural and functional properties and is expected to be used in functional lightweight concrete that can be practically applied in high-rise and large-scale architectural structures. MDPI 2020-10-16 /pmc/articles/PMC7602755/ /pubmed/33081225 http://dx.doi.org/10.3390/polym12102384 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Lim, Taekyung
Lee, Jeong Hui
Mun, Ju-Hyun
Yang, Keun-Hyeok
Ju, Sanghyun
Jeong, Sang-Mi
Enhancing Functionality of Epoxy–TiO(2)-Embedded High-Strength Lightweight Aggregates
title Enhancing Functionality of Epoxy–TiO(2)-Embedded High-Strength Lightweight Aggregates
title_full Enhancing Functionality of Epoxy–TiO(2)-Embedded High-Strength Lightweight Aggregates
title_fullStr Enhancing Functionality of Epoxy–TiO(2)-Embedded High-Strength Lightweight Aggregates
title_full_unstemmed Enhancing Functionality of Epoxy–TiO(2)-Embedded High-Strength Lightweight Aggregates
title_short Enhancing Functionality of Epoxy–TiO(2)-Embedded High-Strength Lightweight Aggregates
title_sort enhancing functionality of epoxy–tio(2)-embedded high-strength lightweight aggregates
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7602755/
https://www.ncbi.nlm.nih.gov/pubmed/33081225
http://dx.doi.org/10.3390/polym12102384
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